A quantum dot confines electronic motion in all three directions. A semiconductor dot can be thin enough that only one transverse subband is occupied, with discrete lateral states controlled by gates. In a rectangular hard-wall model,
A smooth circular lateral confinement is often better approximated by , giving above the transverse ground energy. Shell contains orbitals, twice that many electrons before interactions split the spin degeneracy. Hence closed-shell electron numbers are . These are single-particle quantum numbers; an interacting dot's states are many-electron eigenstates, not simply one orbital occupied by a whole charged island.
A perpendicular magnetic field changes the harmonic spectrum to the Fock-Darwin spectrum. For an electron of charge , take and in the usual symmetric gauge. Then
Reversing the definition of the angular label changes the displayed sign of its orbital term, not the set of energies. The Zeeman term lifts spin degeneracy, while exchange can favor parallel-spin filling in partially filled shells. These effects are distinguished by how peaks evolve with field rather than by identifying every irregular peak spacing with one-particle confinement.
For electrostatics, let and , where represents a fixed offset charge in the chosen convention. The constant interaction model gives
The charging energy is conventionally , whereas adjacent charge-state potentials differ by
This addition energy separates a capacitive contribution from orbital spacing. Exchange, nonuniform screening and correlations are corrections to the constant interaction model; a change in dot shape or effective capacitance can also alter spacings.
Connect the island weakly to source and drain reservoirs through tunnel barriers. sequential tunnelling is suppressed in a charge-stable region when neither adding nor removing an electron is energetically accessible. Sweeping the gate brings a charge electrochemical potential through the reservoir Fermi level, giving a Coulomb-blockade conductance peak. The gate lever arm is , so locally if the capacitances and level spectrum do not vary appreciably. At finite source-drain bias, alignment with either reservoir defines the boundaries of a Coulomb diamond. Its slopes constrain capacitance ratios, and lines parallel to its edges can reveal excited-state transport. The conversion from a diamond's bias height to an energy depends on bias convention; a full-height/half-height factor must not be assumed without declaring the circuit.
A clear charging spectrum requires and tunnel broadening smaller than the relevant addition energy; resolving individual orbital levels additionally requires them smaller than the orbital spacing. Tunnel resistances large compared with suppress strong charge fluctuations in the usual weak-junction regime. Blockade is not an assertion of mathematically zero current: higher-order cotunnelling can remain, and strong coupling or low-temperature spin correlations can invalidate the sequential model. An experimental check therefore combines gate sweeps with bias spectroscopy, temperature dependence and barrier tuning to separate level structure from broadening or uncontrolled charge traps.
In a primary vertical-dot experiment, gate-controlled current oscillations were converted into addition energies using finite-bias diamond spectroscopy; varying magnetic field then followed shell and spin filling. Reproducing enhanced addition energies at electron numbers 2 and 6 in several devices strengthened the shell assignment. The electron temperature was independently estimated above the refrigerator base temperature, an essential distinction when judging spectral resolution. Field-dependent reordering also revealed exchange effects beyond a purely spin-degenerate orbital model.[ref]
Figure 1.
Original constant-interaction charge parabolas and addition-energy example showing charging, spin pairing and shell closure
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