The sum needs a stated interpretation. The original equation leaves the second bond outside explicit parentheses, with its index then formally free. The natural translation-invariant, equal-bond interpretation used here is the energy . The subsequently mentioned has no term in that energy, so no magnetic field or single-ion anisotropy is added. Such an extra term would define another model and change the answer.
Let . Sum over each decorating spin before summing over the remaining spins. The decimation of an alternating mixed-spin chain gives the effective transfer matrix:No on-site entropy has been omitted: the term is the weight of the zero decorating spin. The normalized eigenvectors are , with eigenvaluesThere are transfer steps but physical sites, soThe free energy per two-site unit cell is twice this value. At , the formula gives , as required by two states on one sublattice and three on the other. As , the free energy per physical site tends to , the energy of an aligned chain with two satisfied bonds per unit cell. These checks also fix the factor of two in the site count.
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