In local thermodynamic equilibrium, write the one-ray radiative transfer equation asLarge total optical depth removes the boundary contribution, but an additional local condition is essential: the temperature and opacity vary little over an absorption length . Iterating once in that small gradient givesThe integrated Planck function and its derivative areUsing the specified Rosseland mean opacity, with measured here in inverse length, the source's definition therefore givesThe printed leading term lacks a factor under that definition. An isothermal optically thick medium is a concrete counterexample: gives exactly, while the printed formula gives .
A physical radiative flux requires an angular integral. For direction cosine , the same gradient expansion gives . Integration over all directions gives the net radiative diffusion fluxThe isotropic equilibrium contribution cancels between opposite directions. For comparison the outward-hemisphere flux alone is at this order. None of these consistent definitions yields the printed mixture of coefficients.
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