In Cartesian coordinates, put . Away from the origin the partial derivatives of areSumming the three second partial derivatives yieldsThus is a harmonic function on the punctured space and solves Laplace equation there. The origin is excluded: the singularity cannot be treated as an ordinary harmonic point.
Use the product rule for the divergence of the vector field :The two dot products cancel. Apply the divergence theorem with outward unit normal vector to obtain Green's second identity:Smoothness of the functions and boundary supplies the regularity needed for the divergence theorem.
Assume is an interior point and choose small enough that its closed ball lies inside . Apply Green's second identity to the punctured region , where the potential is smooth and satisfies Laplace equation. Since , this givesThe crucial orientation is the outward unit normal vector of the punctured region: on the inner sphere, it is , pointing toward . Consequently and . The inner boundary term becomesWriting and , its first part tends to by continuity. The second part is because the gradient of is bounded near , and hence tends to zero.
The omitted volume term also tends to zero: for bounded near , its absolute value is bounded by a constant times . Thus the limiting integral exists, and rearranging the outer boundary terms givesThis is Green's third identity for the Poisson equation with the stated sign convention. It retains both boundary terms; no homogeneous boundary condition has been assumed. The punctured-domain calculation accounts for the singular source without incorrectly applying the regular divergence theorem through .
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