Write for the specific gas constant, with the printed denoting the atomic mass unit, and for the radiation constant. In the low-mass envelope the enclosed mass is approximately and the outward luminosity is approximately . The stellar hydrostatic equation, stellar radiative diffusion, and ideal gas equation give
The Kramers' opacity law becomes . Dividing the two differential equations eliminates radius and mass density:
Integrating from a surface matching point gives
Deep compared with the photosphere, the surface terms are negligible. The radiative-zero white-dwarf envelope therefore has
This is the leading envelope approximation used in the later parts, rather than an exact atmospheric boundary condition at .
At the base, temperature, mass density and pressure match the isothermal degenerate core. Let , where is the mean molecular weight per electron. Equating the gas and electron degeneracy pressure gives
Hence . Substituting this into the envelope relation at yields
The matching of a white-dwarf envelope to a degenerate core thus gives , the envelope relation underlying Mestel's cooling law. It depends on pressure as well as mass density continuity at the interface; otherwise the supplied core equation would not determine the matching mass density.
In the radiative-zero white-dwarf envelope, . Substitute this derivative into the stellar hydrostatic equation:
Integrating from the idealized zero-temperature surface at gives
This also gives . A finite surface temperature adds to the integrated profile if the pure power-law pressure relation is retained locally. Near the actual photosphere, the integration constant in the pressure law also matters; the displayed expression is the radiative-zero limit implicit in the printed result and accurate in the deep envelope when .
Apply the preceding temperature profile at the envelope base. Introduce the dimensionless parameter
Then , so the geometrical thickness of a white-dwarf radiative envelope is
The smallness to be established is therefore , up to the numerical factor .
That ordering follows from the cold, strongly electron-degenerate white dwarf model. Throughout the mass-bearing core, , where is the Fermi energy. For nonrelativistic electron degeneracy pressure,
The stellar hydrostatic equation gives a characteristic core of order . Consequently
for fixed composition with order-one molecular-weight ratios, and . Equivalently, the matched base mass density is much lower than a characteristic core mass density, since . The degeneracy ordering applies in the bulk core; at the matching point degeneracy is becoming marginal.
The inequalities and express different facts. The first justifies ignoring surface-temperature terms, while the second makes the envelope geometrically thin. If the core were hot enough that were not small, the exact expression would not justify a thin-layer approximation.
Compare two cooling states of the same white dwarf, holding its mass, nearly temperature-independent degenerate radius and composition fixed. The matching of a white-dwarf envelope to a degenerate core gives , while the geometrical thickness of a white-dwarf radiative envelope gives at leading thin-layer order. Eliminate :
Thus a luminosity drop makes the envelope thinner, with . This is the white-dwarf envelope thickness-luminosity relation. Retaining finite thickness in the radiative-zero model gives the correction
which reduces to the boxed result for .

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