Suppose and . ThenBecause the eigenvalues of are distinct, the eigenspace for is one-dimensional. It follows that , including the possibility . Thus an orthonormal eigenbasis of is also an eigenbasis of . The simplicity of both spectra means their eigenvectors coincide as directions, up to ordering, phases and nonzero scalar multiples.
Conversely, if they share a complete eigenbasis, choose the unitary matrix whose columns are these common normalized eigenvectors. Then and are diagonal, so and . HenceThis is simultaneous diagonalization of the two Hermitian matrices.
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