Use an independent copy of under the product measure . Write , , andSince the pushforward measure of under is , the interaction energy isTwo applications of the chain rule giveThe factor is retained. This classical identity requires differentiation under the integral sign to be justified, just as in part (b). Bounded Hessian matrix of is sufficient, since is integrable; compactly supported endpoints are another sufficient case. The printed quadratic-growth condition alone does not provide this domination.
The failure can occur for the interaction energy too. Take the even interaction potential and replace the endpoint probability measures in part (b) by and . Keep the origin fixed and translate every other atom by one. This coupling is increasing on the line, hence is optimal: its assigned values extend to a nondecreasing transport map, which is the gradient of a convex function. Differences between translated atoms remain integers, so their mutual interaction vanishes. Only interactions with the origin contribute, giving , with from part (b). It therefore also lacks a finite classical second derivative at .
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