Past exam of the physics 2 paper of the University of Oxford / 2015 resit / 1

Take the electric potential to vanish at infinity and work at $r>0$. For a positive point charge $q$ in vacuum,The field is radial and outward. Since a radial scalar function has gradient $\nabla V=(dV/dr)\hat{\mathbf{r}}$,Thus the two expressions have the required vector relationship. Adding an arbitrary constant to $V$ would leave the electric field unchanged; the chosen reference at infinity fixes that constant. The point-charge singularity itself is excluded from the ordinary derivative calculation.