Past exam of the physics A course of the University of Cambridge / 2016 / Paper 1 / Section B / B7

Differentiating the expectation value and using ${\partial }_t|\psi ⟩=-i\hat{H}|\psi ⟩/\hslash$ and ${\partial }_t⟨\psi |=i⟨\psi |\hat{H}/\hslash$ givesThe second term means explicit operator time dependence, distinct from the state's evolution.

The commutator product rule follows by adding and subtracting $\hat{B}\hat{A}\hat{C}$:For the mathematical induction step, let $\hat{D}=[\hat{A},\hat{B}]$ and use $[\hat{A},\hat{D}]=0$. The case $n=1$ is immediate. If $[{\hat{A}}^m,\hat{B}]=m\hat{D}{\hat{A}}^{m-1}$, thenThus the claimed identity holds for every positive integer. Commutation of $\hat{B}$ with $\hat{D}$ is not needed for this particular step. This is the central-commutator differentiation rule. Termwise application to a convergent power series, on a common domain where the operations are justified, gives

For position and momentum, $[\hat{x},\hat{p}]=i\hslash \hat{I}$. Hence $[{\hat{p}}^2,\hat{x}]=-2i\hslash \hat{p}$, $[V(\hat{x}),\hat{x}]=0$ and $[V(\hat{x}),\hat{p}]=i\hslash V^{\prime }(\hat{x})$. Substitution gives Ehrenfest theorem:The mean momentum changes by the mean force. It does not follow for a general nonlinear Potential energy that $⟨V^{\prime }(\hat{x})⟩=V^{\prime }(⟨\hat{x}⟩)$: a closed classical trajectory for the mean position requires an additional condition, such as a quadratic Potential energy or a sufficiently localized wave packet.