Past exam of the physics B course of the University of Cambridge / 2022 / Paper 2 / Section A / A4 / Solution

For a fixed amount of a simple compressible system, write the internal energy as $U(S,V)$. Its exact differential isAssuming the thermodynamic potential has continuous second partial derivatives, equality of its mixed partial derivatives yields the first Maxwell relation:For the second Maxwell relation, use the Legendre transform $H=U+pV$, the enthalpy. Its natural variables are $S,p$ sinceThus $T=(\partial H/\partial S{)}_p$ and $V=(\partial H/\partial p{)}_S$. Equality of the mixed partial derivatives now gives