Past exam of the physics B course of the University of Cambridge / 2022 / Paper 2 / Section A

Interpret the applied pressure as a uniform increase of external hydrostatic pressure on all six faces, and approximate the rock by an isotropic material obeying linear elasticity. Taking tensile stress as positive, ${\sigma }_x={\sigma }_y={\sigma }_z=-p$. By Hooke's law, the strain along any one axis isTo first order in the small strain, the fractional volume change is the sum of the three axial strains:Thus the bulk modulus is $K=40\mathrm{GPa}$. Using the specified Young's modulus, Poisson's ratio, $V=1{\mathrm{m}}^3$ and $p=101325\mathrm{Pa}$ givesThe sign indicates contraction. This is the change relative to the unloaded reference state; simply maintaining a specimen already equilibrated at this same pressure would produce no further change.

Use the pipe-diameter convention for the Reynolds number, with mean velocity $\bar{v}$, density $\rho$ and dynamic viscosity $\mu$:The Reynolds number compares inertial and viscous effects in the fluid flow. A conventional estimate for the onset of turbulence in a pipe is ${\mathrm{Re}}_{\mathrm{crit}}\simeq 2000$, givingHence the usual onset estimate is $\boxed{D\gtrsim 1.6\mathrm{mm}}$. Using the also common transition criterion ${\mathrm{Re}}_{\mathrm{crit}}=2300$ gives $1.84\mathrm{mm}$, whereas $\mathrm{Re}\gtrsim 4000$, used for established turbulence, gives $D\gtrsim 3.2\mathrm{mm}$. There is no universal sharp minimum: inlet disturbances and pipe conditions affect the transition from laminar flow, so the threshold convention must accompany the answer.

(a) Treat the lake as a heat bath at fixed temperature $T_0=288.15\mathrm{K}$ and the block's heat capacity as constant. Its initial temperature is $T_i=473.15\mathrm{K}$, and $C=mc=355\mathrm{J}{\mathrm{K}}^{-1}$. Although the cooling is irreversible, entropy is a state function, so evaluate the block's change along an imagined reversible thermodynamic process:The lake receives heat $Q=C(T_i-T_0)=65675\mathrm{J}$, and thereforeAdding the two contributions givesThe positive result is consistent with the Second law of thermodynamics for heat transfer across a finite temperature difference. The calculation uses $c=710\mathrm{J}\mathrm{k}{\mathrm{g}}^{-1}{\mathrm{K}}^{-1}$ exactly as printed in both the original PDF and the transcription; it does not replace the supplied value by a tabulated value for lead.

(b) The block starts and eventually finishes at the lake's temperature, so its net entropy change is approximately zero. Neglecting buoyancy, air resistance and the final immersion depth, the lost gravitational potential energy $mgh$ becomes internal energy in the lake after the motion and waves have dissipated. The lake remains at $T_0$, givingTemporary heating of the block or temporary storage in kinetic energy does not change this final energy and entropy balance once thermal equilibrium is restored.

For a fixed amount of a simple compressible system, write the internal energy as $U(S,V)$. Its exact differential isAssuming the thermodynamic potential has continuous second partial derivatives, equality of its mixed partial derivatives yields the first Maxwell relation:For the second Maxwell relation, use the Legendre transform $H=U+pV$, the enthalpy. Its natural variables are $S,p$ sinceThus $T=(\partial H/\partial S{)}_p$ and $V=(\partial H/\partial p{)}_S$. Equality of the mixed partial derivatives now gives

Let $N_u,N_l$ be the upper- and lower-level populations and $g_u,g_l$ their degeneracy factors. At thermal equilibrium, the Boltzmann distribution givesNo degeneracy factors are supplied, so the numerical answers use equal degeneracy factors. Stating the ratio as upper population divided by lower population removes an otherwise arbitrary inversion.

(a) At $T=500\mathrm{K}$,The two populations are nearly equal because the level separation is much smaller than the thermal energy $k_{B}T$.

(b) At $T=2\mathrm{mK}=0.002\mathrm{K}$,Almost every atom occupies the lower level. If the levels have unequal degeneracy factors, each boxed ratio must be multiplied by $g_u/g_l$; their individual values cannot be inferred from the paper.