In a photoelectric effect experiment, illuminate a clean metal photocathode with monochromatic light and use a retarding voltage to measure the maximum emitted-electron kinetic energy. The relation has a frequency threshold and a slope . Increasing intensity chiefly changes the number emitted, while increasing frequency increases the available energy per emission. This supports energy transfer in units , with the work function. The retarding-potential measurement distinguishes the electron energy from the photocurrent; the two respond differently to changes of the light.
In electron diffraction, accelerate electrons through a known voltage and measure the angular scattering pattern from a crystal. Distinct diffraction maxima occur where the periodic atomic arrangement gives constructive interference. Their positions give a wavelength through the crystal spacing and diffraction geometry, agreeing with the de Broglie wavelength , with in the nonrelativistic regime. Varying the accelerating voltage shifts the maxima in the predicted way. A localized classical projectile model alone would not explain this wavelength-dependent interference pattern.
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