Past exam of the physics of atmospheres and oceans course of the University of Oxford / 2019 / 2 / d / Solution

Pressure broadening is proportional to collision frequency and therefore becomes small in the upper atmosphere. Doppler broadening remains finite at finite temperature, with a characteristic width of order ${\nu }_0\sqrt{k_{B}T/(m{c}^2)}$ up to the stated width convention. Where that exceeds the collisional width, the line core is Doppler dominated. A Voigt profile combines the two mechanisms; natural broadening can contribute at still lower pressures. Thus a Lorentz pressure-broadened profile cannot hold all the way to $p=0$.

At line centre, replacing the fictitious $1/p$ opacity by a finite Doppler-core coefficient removes the divergent column optical depth. The emitting pressure is then finite rather than arbitrarily close to zero. If that level still lies in the isothermal stratosphere and the core is opaque, the central brightness temperature stays approximately $T_{\mathrm{strat}}$, so the flux floor changes little. If it lies below the stratosphere, or the Doppler-core column becomes thin, warmer layers or the surface contribute and the core brightens. The core-to-wing transition changes shape and width, but Lorentz wings formed mainly at higher pressures remain approximately as in part (c). The size of the correction needs the missing spectroscopic widths, but no unique numerical correction is requested.