The pressure-linear grey opacity model interprets as a mass absorption coefficient. If it is instead a molecular absorption cross section, replace below by that cross section divided by molecular mass. Assume a plane-parallel atmosphere, hydrostatic balance, local thermodynamic equilibrium, and thermal absorption and emission without scattering of light. With height increasing upwards,
Integrating upwards from the surface gives
Thus
The vertical optical depth is dimensionless. The atmosphere is optically thick when and optically thin when . A ray with zenith-angle cosine sees optical depth , so even a vertically thin layer can be opaque along a sufficiently grazing ray.

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