The pressure-linear grey opacity model interprets as a mass absorption coefficient. If it is instead a molecular absorption cross section, replace below by that cross section divided by molecular mass. Assume a plane-parallel atmosphere, hydrostatic balance, local thermodynamic equilibrium, and thermal absorption and emission without scattering of light. With height increasing upwards,Integrating upwards from the surface givesThusThe vertical optical depth is dimensionless. The atmosphere is optically thick when and optically thin when . A ray with zenith-angle cosine sees optical depth , so even a vertically thin layer can be opaque along a sufficiently grazing ray.
It is convenient to use the optical depth above a level,Thermal radiation escapes mainly from levels with of order unity: emission much deeper is attenuated, while the column far above contains little emitting material. Hence, in an optically thick atmosphere,For a particular viewing direction, instead gives . These are characteristic levels, not sharp emitting surfaces; the contribution function depends on the temperature exponent . If , the formal level lies below the surface and the surface itself contributes strongly. A useful estimate then clips at .
Write , , and . The integrated Planck function is by the Stefan–Boltzmann law, andThe formal radiative transfer equation solution for upward radiance at the top isThe first term is transmitted surface emission; the second is emission from the atmosphere. Integrating radiance over the upward hemisphere gives the outgoing radiant flux per unit area,Here is an exponential integral. For fixed and , surface transmission is negligible and the upper limit can be extended to infinity. Positivity permits interchanging the integrals; putting givesConsequently the exact hemispheric optically thick result isThis is a dimensional scale times a dimensionless definite integral depending only on . In the commonly used vertical-ray approximation, define . ThenA vertical-ray approximation therefore has the same scaling but omits the angular factor . Stating which quantity is used prevents a purely angular normalization discrepancy.
At fixed and , the outgoing radiant flux scales as . Increasing the optical depth shifts the effective emitting region to lower pressure and lower temperature. A surface temperature cannot be inferred from emission alone: specify the absorbed stellar radiant flux and impose radiative equilibrium, . If the no-atmosphere blackbody has , thenThe vertical-ray approximation omits from this prefactor. For fixed and sufficiently large optical depth, the surface is warmer than : this is the thermal greenhouse effect within the prescribed temperature profile. It does not by itself establish a self-consistent vertical heating or convection balance.
For , put . Repeated integration by parts gives . The hemispheric thick-limit results areThe second row assumes fixed surface temperature; the third assumes fixed absorbed radiant flux. In the vertical-ray approximation the first of these rows becomes , and the surface temperature factors are the inverse fourth roots.
Thus increasing makes the atmosphere colder at every fixed , decreases outgoing radiation at fixed , and requires a warmer surface at fixed absorbed radiant flux. The case is isothermal and gives exactly, including finite optical depth.
There is an essential approximation limit. The extension of the integral to infinity is valid for fixed as , and is not uniform for arbitrarily large at fixed . The vertical integrand peaks at , so one needs that peak well above the surface in optical depth, with a negligible tail beyond . For example, at the thick formula predicts for but approximately for . This artificial increase contradicts the exact monotonicity: in the finite-optical depth expression every atmospheric emission factor decreases with . At fixed finite , the exact limiting outgoing radiant flux is the transmitted surface term , rather than factorial divergence.
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