For , differentiating the simplified Köhler theory curve gives
The derivative is positive below and negative above it, so is the Köhler activation radius, the unique maximum. At that point , giving
The curve crosses at , reaches at , and approaches from above as . Its formal divergence to negative values as is outside the dilute-chemical solution approximation; a finite dry solute core and composition-dependent properties must replace that extrapolation.
Figure 1.
Köhler equilibrium curve and growth directions at subcritical supersaturation
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