Write and . The nonzero canonical commutation relations arewith cross-species brackets zero. The commutator product rule givesLinearity of the commutator now yields, for the real coefficient ,Strictly, the printed contains an infinite constant in continuum Fock space. Work first with finitely many modes, or replace it by its normal ordering . Their difference is a constant, so every displayed commutator and every conjugation below is unchanged. The latter convention fixes the vacuum state phase without an infinite phase ambiguity.
For a Hermitian operator , the operator exponential is a unitary operator, with . Differentiation and giveWhen , this is the first-order ordinary differential equation with . Multiplication by makes its derivative zero, provingEquivalently, the commutator expansion for exponential conjugation has successive nested commutators , whose exponential series sums to this expression.
Use the combinations at each momentum. Part a gives , , while their creation operators obey , . Applying b givesThe creation operators transform by the Hermitian adjoint formulas with . At , both exponentials are , soSubstituting into the fixed-time mode expansion of a free field of the complex scalar field givesThus exchanges particles and antiparticles, as required for charge conjugation. To see the charge reversal explicitly, the conserved charge obeys . The generator in the question is distinct from this charge.
The two occupation terms in the Hamiltonian are exchanged, with the same relativistic energy , and thereforeIn fact because its mixing terms exchange equal-energy modes. With normal ordering, for . Then fixes the vacuum state and satisfies . The construction is a bosonic species-swap generator.
Take parity symmetry in quantum field theory to preserve free time evolution, so the conjugate initial data reflect along with the field. Substitute the mode expansion of a free field into the defining parity operator relation and change the integration variable . Since , coefficient comparison, or comparison of both the field and its conjugate initial data, gives the intrinsic-even conventionHere parity symmetry in quantum field theory reverses spatial momentum and preserves time. The creation operator formulas follow by taking Hermitian adjoints. The given field relation has fixed the intrinsic phase to .
For one real scalar field, let act on one-particle wave functions by . It is a Hermitian operator with , so is the orthogonal projector onto odd wave functions. Its second quantization is the odd-mode number operatorThe full momentum space is integrated in both expressions; the factors prevent double counting the pairs . A suitable parity operator isFor verification, . Thus the even combination is unchanged, and the odd combination changes sign under conjugation by , exactly reproducing . The same holds for creation operators. The odd-mode number operator has integer eigenvalues, so , and . Multiplying by an overall constant phase would not change its conjugation action. This is parity as odd-mode number parity.
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