Take an overdamped particle with viscous drag coefficient γ, so its deterministic drift in the harmonic potential U=kx2/2 is x˙=−kx/γ. The one-dimensional Fokker-Planck equation has probability currentAt thermal equilibrium, J=0 and the Boltzmann distribution is p(x)=Z−1e−kx2/(2kBT), with p′/p=−kx/(kBT). Inserting this into the zero-current condition givesThe result is the Einstein diffusion relation between diffusion and mobility. It assumes a bath at one temperature, linear drag and thermal equilibrium. The same Gaussian probability density gives ⟨x2⟩=kBT/k, providing an independent calibration of trap stiffness.
J=−γkxp−Ddxdp.
0=kxp(−γ1+kBTD),D=γkBT.
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