At 7000K, kBT=0.603eV andThe 2p ground term has fine-structure levels J=1/2 and J=3/2, with energy-level degeneracy g1=2 and g2=4. Detailed balance gives C21=C12(g1/g2)eΔE/(kBT)=7.17×10−14m3s−1. The critical density is thereforeWith collisions and spontaneous decay both retained, N2/N1=neC12/(A21+neC21). A Boltzmann distribution, N2/N1→2e−ΔE/(kBT)≃1.97, requires ne≫ncrit, not merely equality. For example ne≳3×108m−3 brings the ratio within about ten per cent of that limit.
C12=1.415×10−13m3s−1,ne=C120.007A21=1.13×105m−3=0.113cm−3.
ncrit=A21/C21=3.19×107m−3≃32cm−3.
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