Population can move between the levels by electron-impact excitation and de-excitation, spontaneous emission, radiative absorption and stimulated emission. Other collision partners and radiative cascades can matter in a fuller atom. In the elementary coronal approximation, the plasma is dilute, optically thin, steady, and weakly illuminated at the transition frequency. Electron impacts predominantly excite the lower level, while spontaneous emission predominantly empties the upper level; collisional de-excitation and photon trapping are negligible. The population balance isA key condition is neC21≪A21, together with insignificant external pumping and competing channels. A Maxwellian electron Maxwell-Boltzmann distribution lets the tabulated rate coefficient be expressed using one temperature.
neC12N1=A21N2,N1N2=A21neC12.
At 7000K, kBT=0.603eV andThe 2p ground term has fine-structure levels J=1/2 and J=3/2, with energy-level degeneracy g1=2 and g2=4. Detailed balance gives C21=C12(g1/g2)eΔE/(kBT)=7.17×10−14m3s−1. The critical density is thereforeWith collisions and spontaneous decay both retained, N2/N1=neC12/(A21+neC21). A Boltzmann distribution, N2/N1→2e−ΔE/(kBT)≃1.97, requires ne≫ncrit, not merely equality. For example ne≳3×108m−3 brings the ratio within about ten per cent of that limit.
C12=1.415×10−13m3s−1,ne=C120.007A21=1.13×105m−3=0.113cm−3.
ncrit=A21/C21=3.19×107m−3≃32cm−3.
Assume a cold, unmagnetized, weakly collisional plasma, a small fractional bandwidth and ω≫ωp. The dispersion relation is ω2=c2k2+ωp2, with ωp2=nee2/(ϵ0me). The group velocity and propagation time areThe lower frequencies arrive later. Taking the magnitude of the frequency derivative over Δω givesFor a nonuniform line of sight, replace neL by the dispersion measure ∫nedl. The light travels at the group velocity, not at the phase velocity.
vg=dkdω=c1−ω2ωp2,τ(ω)=cL(1−ω2ωp2)−1/2≃cL(1+2ω2ωp2).
Δτ≃cω3LΔωϵ0menee2.
Use the preceding electron density as the line-of-sight mean, L/c=2000yr, ω=2π(1.4×109)s−1 and Δω=2π(4.0×107)s−1. ThenThis estimate corresponds to dispersion measure about 69.5pccm−3. A cloud density inferred from absorption need not equal the actual path average, so a real pulsar may differ even at the same distance.
Δτ≃8.4×10−3s=8.4ms.
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