Population can move between the levels by electron-impact excitation and de-excitation, spontaneous emission, radiative absorption and stimulated emission. Other collision partners and radiative cascades can matter in a fuller atom. In the elementary coronal approximation, the plasma is dilute, optically thin, steady, and weakly illuminated at the transition frequency. Electron impacts predominantly excite the lower level, while spontaneous emission predominantly empties the upper level; collisional de-excitation and photon trapping are negligible. The population balance is
A key condition is , together with insignificant external pumping and competing channels. A Maxwellian electron Maxwell-Boltzmann distribution lets the tabulated rate coefficient be expressed using one temperature.
At , and
The ground term has fine-structure levels and , with energy-level degeneracy and . Detailed balance gives . The critical density is therefore
With collisions and spontaneous decay both retained, . A Boltzmann distribution, , requires , not merely equality. For example brings the ratio within about ten per cent of that limit.
Assume a cold, unmagnetized, weakly collisional plasma, a small fractional bandwidth and . The dispersion relation is , with . The group velocity and propagation time are
The lower frequencies arrive later. Taking the magnitude of the frequency derivative over gives
For a nonuniform line of sight, replace by the dispersion measure . The light travels at the group velocity, not at the phase velocity.
Use the preceding electron density as the line-of-sight mean, , and . Then
This estimate corresponds to dispersion measure about . A cloud density inferred from absorption need not equal the actual path average, so a real pulsar may differ even at the same distance.

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