With Aμ=(0,A), the lowered components are Aμ=(0,−A). Define π=−i∇+eA and B=∇×A. This convention describes physical charge q=−e. Since Fij=−ϵijkBk,Writing ψ=e−i(m+E)tϕ makes the squared equationDrop E2 relative to 2mE and write ϕ=(φ,χ)T. Both two-component blocks obey the Pauli equationThe gauge-covariant kinetic term contains p2/(2m), e(A⋅p+p⋅A)/(2m), and e2A2/(2m): free kinetic, orbital magnetic, and diamagnetic contributions. The spin term is −μ⋅B with μ=−eσ/(2m), giving spin gyromagnetic factor g=2 at this order. In uniform B and symmetric gauge, the orbital term is eB⋅L/(2m).
σμνFμν=−2(σ⋅B00σ⋅B).
[(m+E)2−m2−π2−eΣ⋅B]ϕ=0.
Eφ=[2m(p+eA)2+2meσ⋅B]φ,Eχ=[2m(p+eA)2+2meσ⋅B]χ.
Squaring introduces extra formal solutions unless the original first-order equation is retained. In the usual positive-energy Dirac basis it relates the small lower component to the upper one by χ=(σ⋅π)φ/(2m+E)≃(σ⋅π)φ/(2m). Thus these are not two independent nonrelativistic particles. Restoring units places ℏ in the spin term, eℏσ⋅B/(2m).
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