Work with and . Multiplying the free Dirac equation by the operator with the opposite mass sign gives
The ordinary derivatives commute, so only the symmetric part of contributes. Requiring this operator to factor the Klein-Gordon equation, , for arbitrary free momenta gives
Thus the Dirac matrices represent the corresponding Clifford algebra. The inference uses factorization for the general free equation; the fact that one specially chosen wavefunction happens to solve both equations would not alone determine every matrix anticommutator.
Let , , and . Direct differentiation in the gauge covariant derivative gives
The gradient of the local phase is exactly cancelled by the potential transformation. Since is scalar in spinor space and commutes with the Dirac matrices,
Consequently a solution is mapped into a solution: the minimally coupled Dirac equation is covariant under the local U(1) gauge symmetry. The operator and wavefunction both transform; ordinary differentiation of the transformed wavefunction alone would leave an extra phase-gradient term.
Use . The stated derivative convention gives . Also . Splitting products into symmetric and antisymmetric parts therefore yields
Multiplying the first-order equation by now gives
The antisymmetric derivative commutator is the electromagnetic field strength. It is the extra term absent when squaring an uncoupled Dirac operator with commuting derivatives, and it generates the spin–magnetic-field interaction in the nonrelativistic limit.
With , the lowered components are . Define and . This convention describes physical charge . Since ,
Writing makes the squared equation
Drop relative to and write . Both two-component blocks obey the Pauli equation
The gauge-covariant kinetic term contains , , and : free kinetic, orbital magnetic, and diamagnetic contributions. The spin term is with , giving spin gyromagnetic factor at this order. In uniform and symmetric gauge, the orbital term is .
Squaring introduces extra formal solutions unless the original first-order equation is retained. In the usual positive-energy Dirac basis it relates the small lower component to the upper one by . Thus these are not two independent nonrelativistic particles. Restoring units places in the spin term, .
Far from a short-range potential, the particle is locally free. The imposed incoming boundary condition is a unit-amplitude plane wave travelling along , while an outgoing free spherical wave has radial dependence . The scattering coefficient can depend on direction, giving
For the Schrödinger probability current, , the incident flux is . The outgoing scattered radial flux, separated from the incident beam, is . Thus the outgoing rate through , divided by incident flux, gives
This elastic-scattering result uses the same incoming and outgoing wavenumber and the usual outgoing-wave boundary condition.
The spherical potential has a rotationally symmetric Fourier transform, so choose the polar axis of the integration along . With ,
The first Born approximation therefore gives
There is no azimuthal dependence. At , the bracket is , so is finite, not zero. The approximation assumes scattering weak enough for the incident plane wave to replace the distorted wave inside the interaction integral.
Apart from the finite forward limit, amplitude zeros obey , or , where . The first positive root is . Since the accessible range is ,
Thus there are no zeros for ; the first enters at the largest momentum transfer, , when .
For larger roots, lies just below , . Expanding gives . Keeping its leading term yields the requested diffraction estimate
Exactly, replace the numerator by the corresponding root . The displayed approximation is a large- root approximation: taking large at fixed low order does not make equal to . For example, the exact first angle at high is approximately , not .
Figure 1.
Born scattering form factor of a spherical constant potential
. The exact normalized amplitude and its first three zeros are shown. The asymptotic half-integer-pi locations are close estimates, with a visible low-order correction. Details.
Assume the scalar potential is real, so the Weyl equation has a Hermitian Hamiltonian . Multiplying the equation and its adjoint by and respectively gives
Thus with and , the lower-index four-current obeys .
For ,
Consequently is conserved for spatially constant ; a spatially uniform time-dependent scalar offset would also commute with it. For general nonuniform it is not conserved. At nonzero momentum, , so the helicity eigenvalues are . In the chosen constant-potential Weyl Hamiltonian, the positive branch has helicity ; the negative branch has . An expectation value in a superposition need not itself be an eigenvalue.
For dependence on alone and constant , remove the common phase by . Then . The normalized eigenvectors
obey . The corresponding first-order transport equations have characteristics and , respectively, giving
Here propagates toward and toward , both at unit speed.
For a fixed unit vector , replace by and choose orthonormal spinors satisfying . If , one choice is
Independent constant phases on the spinors can be absorbed into the two arbitrary envelope functions.
Evaluate the envelopes at their displayed arguments and set . The common phase cancels from every bilinear. Direct use of the Pauli matrices gives
The physical longitudinal current is : the two density profiles move in opposite directions. Their separate transport identities give .
For a coherent superposition, the transverse currents and generally do not vanish. They are independent of , so they contribute no divergence in this one-dimensional construction. Omitting them would give an incorrect local four-current. Pointwise, , so the pure two-component Weyl current is future null wherever the density is nonzero. If only one envelope is present, the current points entirely along its propagation direction; an incoherent average can remove the transverse interference terms.

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