Work with η=diag(1,−1,−1,−1) and ∂=γμ∂μ. Multiplying the free Dirac equation by the operator with the opposite mass sign givesThe ordinary derivatives commute, so only the symmetric part of γμγν contributes. Requiring this operator to factor the Klein-Gordon equation, (∂μ∂μ+m2)ψ=0, for arbitrary free momenta givesThus the Dirac matrices represent the corresponding Clifford algebra. The inference uses factorization for the general free equation; the fact that one specially chosen wavefunction happens to solve both equations would not alone determine every matrix anticommutator.
(i∂+m)(i∂−m)ψ=[−γμγν∂μ∂ν−m2]ψ=0.
{γμ,γν}=2ημνI,{γμ,γν}=2ημνI.
Let U(x)=eieα(x), ψ′=Uψ, and Aμ′=Aμ+∂μα. Direct differentiation in the gauge covariant derivative givesThe gradient of the local phase is exactly cancelled by the potential transformation. Since U is scalar in spinor space and commutes with the Dirac matrices,Consequently a solution is mapped into a solution: the minimally coupled Dirac equation is covariant under the local U(1) gauge symmetry. The operator and wavefunction both transform; ordinary differentiation of the transformed wavefunction alone would leave an extra phase-gradient term.
Dμ′ψ′=(∂μ−ieAμ′)(Uψ)=U[∂μ+ie∂μα−ieAμ−ie∂μα]ψ=UDμψ.
(iγμDμ′−m)ψ′=U(iγμDμ−m)ψ.
Use Fμν=∂μAν−∂νAμ. The stated derivative convention gives [Dμ,Dν]=−ieFμν. Also [γμ,γν]=−2iσμν. Splitting products into symmetric and antisymmetric parts therefore yieldsMultiplying the first-order equation by iγμDμ+m now givesThe antisymmetric derivative commutator is the electromagnetic field strength. It is the extra term absent when squaring an uncoupled Dirac operator with commuting derivatives, and it generates the spin–magnetic-field interaction in the nonrelativistic limit.
(γμDμ)2=DμDμ+41[γμ,γν][Dμ,Dν]=D⋅D−2eσμνFμν.
[−D⋅D+2eσμνFμν−m2]ψ=0.
With Aμ=(0,A), the lowered components are Aμ=(0,−A). Define π=−i∇+eA and B=∇×A. This convention describes physical charge q=−e. Since Fij=−ϵijkBk,Writing ψ=e−i(m+E)tϕ makes the squared equationDrop E2 relative to 2mE and write ϕ=(φ,χ)T. Both two-component blocks obey the Pauli equationThe gauge-covariant kinetic term contains p2/(2m), e(A⋅p+p⋅A)/(2m), and e2A2/(2m): free kinetic, orbital magnetic, and diamagnetic contributions. The spin term is −μ⋅B with μ=−eσ/(2m), giving spin gyromagnetic factor g=2 at this order. In uniform B and symmetric gauge, the orbital term is eB⋅L/(2m).
σμνFμν=−2(σ⋅B00σ⋅B).
[(m+E)2−m2−π2−eΣ⋅B]ϕ=0.
Eφ=[2m(p+eA)2+2meσ⋅B]φ,Eχ=[2m(p+eA)2+2meσ⋅B]χ.
Squaring introduces extra formal solutions unless the original first-order equation is retained. In the usual positive-energy Dirac basis it relates the small lower component to the upper one by χ=(σ⋅π)φ/(2m+E)≃(σ⋅π)φ/(2m). Thus these are not two independent nonrelativistic particles. Restoring units places ℏ in the spin term, eℏσ⋅B/(2m).
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