At half ionization, electron and neutral densities are each n0/2, so the left side of Saha's equation is n0/2. Its logarithm changes by dlogn0=(3/2+R/(kBT′))dlogT′. To first order,This holds for small fractional changes and the supplied ground-state partition approximation, not an exact finite-difference identity.
n0Δn0≃(23+kBT′R)T′ΔT′.
The measured ratio is ten, so R/(kBT′)=8.5. Taking R=13.6 eV gives kBT′=1.60 eV or T′≃1.86×104 K. Substitute into Saha's equation:Higher density favors recombination and reduces the entropy advantage of free electrons at a fixed ionized fraction, so a higher temperature is required. The ratio 8.5 means half ionization does not require kBT to equal the ionization energy: translational phase space and the exponential tail are important.
n0=2h3(2πmekBT′)3/2e−8.5≃2.49×1024 m−3.
Hydrogen's n=2 excitation energy is 3R/4=10.2 eV. With electronic degeneracy ratio g2/g1=4, its relative population is 4e−10.2/1.60≃6.8×10−3. Thus the first excited manifold contributes below one percent of the ground population at the inferred temperature, explaining the leading ground-state approximation.
There is a qualification to extending this argument to infinitely many Rydberg states: the isolated-atom partition sum with degeneracy 2n2 formally diverges. Plasma screening and level dissolution impose a physical cutoff. The small low-lying populations justify the simple approximation in its intended regime, not an unrestricted infinite partition sum.
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