Past exam of the soft condensed matter course of the University of Cambridge / 2012 / Paper 1 / 4 / a

In linear viscoelasticity, stress is a linear functional of past strain increments: scaling the deformation scales the response, and responses to small deformations add. For a time-translation-invariant material, Boltzmann superposition writes $\sigma (t)={\int }_{-\infty }^{t}G(t-s)\dot{ϵ}(s)ds$, where $G$ is a relaxation modulus. The material combines reversible storage with delayed or dissipative response; the description is restricted to small deformations about the chosen state.

The Maxwell model places an elastic spring and viscous dashpot in series. They carry the same shear stress $\sigma$, and their shear strains add:Differentiating givesHere $ϵ$ is dimensionless shear strain, $\sigma$ shear stress in pascals, $G_0$ the spring shear modulus, $\eta$ dashpot viscosity in $\mathrm{Pa}\mathrm{s}$, and $\tau$ the relaxation time. The first term describes changing elastic strain; the second is viscous flow. In this model the material flows at long times and has zero static shear modulus.