Every nonidentity rotation has order five. The reflections are the five order-two elements, since (Rjm)2=RjR−j=I.
The reflection Rjm has axis at angle jπ/5 to the horizontal, understood modulo π. If vertices have angles 2kπ/5, it sends vertex k to vertex j−k(mod5). Each axis passes through one vertex and the midpoint of the opposite edge; that vertex stays fixed and the other four vertices exchange in two pairs.