Spontaneous symmetry breaking means that a pure thermodynamic phase is less symmetric than the Hamiltonian even when the selecting external field is removed. For example,The direction of the infinitesimal field is held fixed in this limit. Reversing the limits in a finite symmetric sample normally gives zero. For the XY model, an ordered state chooses one direction from a circle of energetically equivalent directions.
A Goldstone mode is a long-wavelength fluctuation along this continuously degenerate family. A uniform angle rotation costs no energy; a slowly varying one costs only gradient energy. In the stated static phase-only model the quadratic kernel is , tending to zero as . There is one independent soft order-parameter phase coordinate for broken rotation. The static Hamiltonian does not specify a dynamical dispersion ; that requires a dynamical law. Magnitude fluctuations instead have a restoring local curvature and have been excluded from this low-energy model.
Pure thermodynamic phase Created 2026-10-06 Updated 2026-10-14
A pure thermodynamic phase is an extremal equilibrium Gibbs state rather than a probabilistic mixture of distinct macroscopic phases. On an ordered Ising branch, taking the thermodynamic limit before removing a selecting conjugate field gives a nonzero magnetization. A symmetric mixture can instead have zero mean but a nondecaying two-point contribution. The connected correlation function and correlation length describing ordinary critical fluctuations should be evaluated in a chosen pure phase when this distinction matters.
In a symmetric equal mixture of two ordered pure thermodynamic phases with magnetizations , the mean spin vanishes but the large-distance two-spin expectation tends to . Thus the connected correlation function of the mixture has a nondecaying part. The correlation-function susceptibility sum rule gives an extensive contribution to susceptibility per spin. This is phase-switching response, not the connected susceptibility within one pure phase. The latter uses the thermodynamic limit followed by a one-sided zero-field limit, and subtracts the nonzero pure-phase mean before defining the correlation length.
Thermodynamic phase 2026-10-14
A thermodynamic phase is a form of macroscopic equilibrium characterized by its structure, symmetries and thermodynamic response. Away from phase transitions, its free-energy density varies smoothly with the control parameters. Different phases can share a phase coexistence boundary. An ordered magnetic phase is distinguished from a disordered phase by its spontaneous order parameter; positive and negative ordered states are different pure thermodynamic phases related by spin inversion symmetry.