Correlation-function susceptibility sum rule ($\chi ={\beta }_{\mathrm{th}}{\sum }_{r}G(r)$)

When an energy Hamiltonian contains $-h{\sum }_n{\sigma }_n$, differentiating its partition function gives $\chi =({\beta }_{\mathrm{th}}/N)\mathrm{Var}({\sum }_n{\sigma }_n)$. Translation invariance converts this to the connected-correlation sum. A dimensionless source ${\beta }_{\mathrm{th}}h$ removes the explicit inverse-temperature factor. In continuum physical coordinates the lattice sum includes the site-density factor $a^{-D}$. A selected pure thermodynamic phase is needed below an ordered transition to avoid a macroscopic mixture contribution.

In a symmetric equal mixture of two ordered pure thermodynamic phases with magnetizations $\pm M_0$, the mean spin vanishes but the large-distance two-spin expectation tends to $M_0^2$. Thus the connected correlation function of the mixture has a nondecaying part. The correlation-function susceptibility sum rule gives an extensive contribution ${\beta }_{\mathrm{th}}N{M}_0^2$ to susceptibility per spin. This is phase-switching response, not the connected susceptibility within one pure phase. The latter uses the thermodynamic limit followed by a one-sided zero-field limit, and subtracts the nonzero pure-phase mean before defining the correlation length.