Project a quantized field onto two low-energy orbitals. A sufficient regime has temperature, hopping and interaction shifts small compared with the energy gap to discarded orbitals. Small interwell contact interaction integrals can then be neglected while retaining a small quantum tunnelling matrix element. The projected field's operator commutator is the two-mode projection operator kernel, rather than a complete spatial Dirac delta function.
Two localized orbitals coupled by quantum tunnelling and on-site interactions give the smallest Bose-Hubbard model. A symmetric double-well potential with lowest one-particle energies has and common diagonal energy . At fixed total particle number, that common diagonal term is constant. A fixed-number two-mode condensate gives a simple variational method for this model, while stronger interactions can require occupation-correlated trial quantum states.
Wavefunction matching at a finite potential step Created 2026-10-18 Updated 2026-10-20
For a finite jump in a one-dimensional potential energy, with constant mass and no delta potential, both the wavefunction and its first spatial derivative are continuous. Integrating the time-independent Schrödinger equation across a vanishing interval makes the jump in vanish, since the integral of vanishes. A jump in itself would produce a derivative of a Dirac delta function in , with no matching term in the equation. The second derivative can jump. This matching allows transmission and quantum tunnelling; a finite step is not a hard wall.