Let and use a fixed arbitrary material subvolume in the reference configuration, with outward unit normal . The reference mass density is time independent. The global momentum conservation law is
The divergence theorem, differentiation under the integral, and arbitrariness of give
The global conservation of energy law includes both internal energy and kinetic energy:
Here is outgoing heat flux per reference area. Localizing gives
Subtract the scalar product of the local momentum conservation law with . Since , this proves the Lagrangian internal energy balance
For positive temperature , the global entropy inequality is
Its local excess is a nonnegative production density . Expanding the divergence of proves the Lagrangian entropy inequality in the requested equality form:
No constitutive assumption on the heat flux was needed for these balance identities.
For the reference-configuration jump balances, make the orientation convention explicit. Write and let point from the minus side to the plus side. Let be the actual interface speed in direction . A signed level function with the plus side obeys on the interface. For , the singular time derivative is ; the singular reference divergence of is . Thus a local conservation law bounded sources has the Rankine-Hugoniot condition
This is also the shrinking moving-pillbox calculation of the global law: finite volume supplies have no surviving surface term.
To match the displayed positive-sign momentum jump in the paper, use its speed parameter as , so the interface travels in direction . Assuming continuous and no surface force or energy supply, the jump laws are then
and, from ,
The last inequality is nonnegative entropy production concentrated on the interface. Temperature and flux in the entropy term are the traces on their respective sides; one cannot take a common temperature outside the jump unless it is continuous.
If is instead defined as the interface speed in direction , all three terms above acquire a minus sign. In particular the printed positive-sign momentum formula requires the opposite speed convention; changing just the order of the jump does not remove this convention issue. If reference density is discontinuous, replace by the jump of the complete conserved density.
An equivalent internal-energy jump follows by subtracting the kinetic-energy jump using , where :
The averaged traction appears because ; using a one-sided traction would generally be incorrect.