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The refractive index compares the phase velocity of light in a medium with the vacuum speed of light $c$. For a transparent, uniform medium with isotropy and a positive-index propagation branch,Here $\omega >0$ is the angular frequency, $k>0$ is the wavenumber, and $v_{\mathrm{ph}}=\omega /k$ is the speed of a surface of constant wave phase. The refractive index is a dimensionless quantity; it is a property of a specified material response at a specified frequency, rather than a universal number attached to the word “glass”. More general absorbing or negative-index media require the conventions discussed in refractive index and electromagnetic response. ^[ref]

For an original model example, choose $n=3/2$ at vacuum wavelength ${\lambda }_0=600\mathrm{nm}$. The phase velocity is $v_{\mathrm{ph}}=2c/3\simeq 1.999\times 10^{8}m/s$, the frequency is $f=c/{\lambda }_0\simeq 4.997\times 10^{14}\mathrm{Hz}$, and the medium wavelength is $400\mathrm{nm}$. These are stipulated model values, not measured properties of glass or water. A value at this single frequency does not determine a pulse's group velocity.

The usefulness of refractive index is that one measured response connects several different observations: Snell's law predicts refraction, optical path length predicts accumulated wave phase, and changes with frequency describe optical dispersion. Even at normal incidence, where a light ray does not bend, a changed refractive index changes wavelength and wave phase. The following comparison isolates that effect; the oblique geometry is developed in wavefront.

For a uniform linear medium with isotropy and local constitutive response, Maxwell equations give $k^2={\omega }^2\epsilon (\omega )\mu (\omega )$. Here $\epsilon$ is permittivity and $\mu$ is magnetic permeability. Since $c^{-2}={\epsilon }_0{\mu }_0$, the relative permittivity ${\epsilon }_r=\epsilon /{\epsilon }_0$ and the relative magnetic permeability ${\mu }_r=\mu /{\mu }_0$ obeyIf both responses are real and positive with negligible loss, and the ordinary positive-index branch is intended, then $n=+\sqrt{{\epsilon }_r{\mu }_r}$. If additionally ${\mu }_r\simeq 1$, then $n\simeq \sqrt{{\epsilon }_r}$. All these responses must be evaluated at the electromagnetic wave's frequency; a static relative permittivity cannot simply be substituted at an optical frequency. ^[ref]

With loss, use a complex index $\tilde{n}=n^{\prime }+i\kappa$ and explicitly fix the phase convention for complex amplitudes. For $E\propto \exp [i(kz-\omega t)]$ with $k=\tilde{n}\omega /c$, its wave amplitude has factor $\exp (-\kappa \omega z/c)$. A forward attenuating branch has $\kappa \ge 0$, while its wave phase is controlled by $n^{\prime }$. The complex relation ${\tilde{n}}^2={\epsilon }_r{\mu }_r$ alone leaves a choice of sign: the physical solution also needs causality and the appropriate radiation or decay condition. In negative-index media the physically selected real part can be negative. The positive square root is therefore not a universal rule for complex or negative-index media. Direction and polarization of an electromagnetic wave also matter in a plane wave in an anisotropic dielectric, for which one scalar index need not describe every propagation branch.