Spectral function ($\rho (\omega )$)

The spectral function records the weighted energy differences connected by an operator. With the convention $G_R=-i\theta ⟨[A,A]⟩$, it is proportional to $-\mathrm{Im}{G}_R$.

A normalized retarded amplitude $G^R(\mathbf{k},t)=-i\Theta (t)e^{-i{\Omega }_{\mathbf{k}}t-{\Gamma }_{\mathbf{k}}t}$, with constant ${\Gamma }_{\mathbf{k}}>0$, has Fourier transform $G^R(\mathbf{k},\omega )=(\omega -{\Omega }_{\mathbf{k}}+i{\Gamma }_{\mathbf{k}}{)}^{-1}$. Consequently $A=-\mathrm{Im}{G}^R/\pi$ is the displayed positive Lorentzian line shape, of unit frequency integral. Its maximum is at ${\Omega }_{\mathbf{k}}$ and its half width at half maximum is ${\Gamma }_{\mathbf{k}}$. The energy half-width is $\hslash {\Gamma }_{\mathbf{k}}$. Amplitude decays on time $1/{\Gamma }_{\mathbf{k}}$ whereas probability decays on time $1/(2{\Gamma }_{\mathbf{k}})$. A general interacting electron has quasiparticle residue $Z$ and incoherent spectral weight in addition to this normalized local pole model; frequency-dependent width or self-energy can invalidate a global Lorentzian.

The electron single-particle spectral function $A(\mathbf{k},ϵ)=-\mathrm{Im}{G}^R(\mathbf{k},ϵ)/\pi$, in a convention normalized to unit energy integral per orbital and spin, describes addition and removal energies. For the fermionic retarded Green function, $G^R(\mathbf{k},t)=-i\Theta (t)⟨\{c_{\mathbf{k}}(t),c_{\mathbf{k}}^{†}(0)\}⟩$, energy is referenced to the chemical potential. The occupied removal spectrum is $f(ϵ)A(\mathbf{k},ϵ)$, with Fermi-Dirac distribution $f$. In the noninteracting limit, $A$ is a delta peak at the band energy; interactions can shift, broaden, and redistribute its weight.

The fluctuation-dissipation theorem relates an equilibrium correlation function to the dissipative part of the corresponding linear response. If $\rho =-2\mathrm{Im}{G}_R$, one common convention is $S(\omega )=\rho (\omega )/(1-e^{-\omega /T})$, which becomes $S(\omega )\simeq T\rho (\omega )/\omega$ in the classical limit $|\omega |\ll T$.

A Matsubara correlator is obtained from the retarded spectral density by a Cauchy transform evaluated at an imaginary frequency.