The Spectral profile records the energy needed to concentrate a function on sets of a given stationary mass. For a finite irreducible Reversible Markov chain with Stationary distribution , define
Here is its Dirichlet form of a Markov chain, and ensures that admissible nonempty sets exist. This is the variance-normalized convention.[ref]
The profile is nonincreasing in , because enlarging permits more supports. The ordinary spectral gap is a lower bound on every , but small supports can force a larger Rayleigh quotient. For the symmetric two-state chain with off-diagonal Transition probability , a function supported on one state has energy and variance , so .
The denominator matters. Replacing variance by gives a restricted Dirichlet eigenvalue instead. On a support of mass at most , the Cauchy-Schwarz inequality gives , relating the two conventions within a factor .
For a finite irreducible Reversible Markov chain with Stationary distribution , let and define its conductance profile by
For and the variance-normalized Spectral profile,
The star here names the small-set profile on this restricted domain; some sources reserve a star for its extension truncated at .[ref]
For the upper bound, test the spectral-profile quotient with . Its energy is and its variance is . For the lower bound, take a nonnegative function supported on a set of mass at most . Applying the level-set integral identity to bounds by . Factoring the difference of squares and applying the Cauchy-Schwarz inequality bounds this last expression by . Squaring and using proves the lower bound. Thus a geometric obstruction to boundary flow produces an analytic obstruction to relaxation.

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