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Energy dependence of water equivalence means that a material can approximate water for one radiation energy or spectrum yet differ for another. A water-equivalent material must therefore be characterized for the interaction and radiation conditions of interest, rather than by one density or one transmission comparison.

For primary photon attenuation, defineusing the material and water mass attenuation coefficients. Equal surface mass densities give equal primary transmission only when this coefficient ratio is one. Changing slab thickness can match one selected energy, but cannot generally make $Q_{\mu }(E)$ constant at all energies.

A concrete example uses the primary NIST tables for liquid water and PMMA. Their mass attenuation coefficients, in $\mathrm{c}{\mathrm{m}}^2/g$, areso the PMMA-to-water ratios are about $0.80724$ at $30\mathrm{keV}$ and $0.96134$ at $100\mathrm{keV}$. These are material data at specified photon energies, not an assertion that PMMA is a universally equivalent substitute.^[ref]

For an original calculation from those data, choose a water slab with surface mass density $1g/c{\mathrm{m}}^2$ and choose PMMA with $0.1707/0.1641\approx 1.04022$ times that value. Their Beer-Lambert law optical depths then agree at $100\mathrm{keV}$. At $30\mathrm{keV}$, however, the PMMA optical depth is only about $0.83971$ of the water value. The primary transmitted fractions become $e^{-0.3756}\approx 0.68688$ for water and $e^{-0.31539}\approx 0.72950$ for the adjusted PMMA slab. Matching one row of the table did not match another.

The interaction being matched also matters. A mass energy-absorption coefficient concerns retained energy, while a mass attenuation coefficient concerns removal of primary photons from a beam. Matching the latter does not by itself match absorbed dose. A beam containing several photon energies introduces a spectrum-weighted water-equivalence ratio, which can change when those contributions change.

A proposed physical comparison uses the same characterized detector and irradiation geometry while varying the incident photon energy or filtration. Measure slab density and thickness, and compare both primary transmission and the relevant energy-deposition response. The NIST coefficients provide interaction data; scattering from the surrounding apparatus and the detector's own energy response remain separate parts of that experiment.

A radiation physicist who coauthored NIST tables of mass attenuation coefficients and mass energy-absorption coefficients with Stephen M. Seltzer. The tables connect X-ray and gamma ray photon energy to interactions in elements and mixtures. They distinguish removal of photons from a beam from absorption of their energy, a difference needed when calculating shielding or deposited radiation energy.^[ref]

For a narrow, well-collimated photon beam, scattered photons are rejected and the uncollided intensity obeys the Beer-Lambert law, $I(x)=I(0)e^{-\mu x}$. With water mass density $\rho \simeq 1\mathrm{g}\mathrm{c}{\mathrm{m}}^{-3}$, the linear attenuation coefficient is $\mu =\rho (\mu /\rho )$. The half-value layer is thereforeThus the annihilation photons associated with the fluorine-18 source require about $1.60$ times as much water for the same attenuation as the technetium-99m photons. The $511\mathrm{keV}$ here is the annihilation photon energy, not the variable kinetic energy of an emitted Positron. A broad-beam measurement admitting scattered photons would require a buildup correction and would not have this simple transmission interpretation.^[ref]

For photons, the total mass attenuation coefficient sums contributions from photoelectric absorption, Compton scattering, coherent Rayleigh scattering, and pair production in nuclear or electronic fields when above their thresholds. At sufficiently high photon energies, photonuclear reactions can also contribute. Attenuation counts removal from the incident narrow beam, including scattering without complete local deposition of the original energy.

In water at both specified energies, Compton scattering dominates. At $140\mathrm{keV}$, photoelectric absorption and coherent Rayleigh scattering make smaller contributions; at $511\mathrm{keV}$ these are still less important. Nuclear-field pair production is impossible below $2m_e{c}^2=1.022\mathrm{MeV}$, so it occurs in neither example. The positrons used to produce the fluorine-18 annihilation radiation do not change that threshold for interactions of its $511\mathrm{keV}$ photons in water.

Strictly, $\mu$ is a linear attenuation coefficient, whereas $\mu /\rho$ is a mass attenuation coefficient; the source's wording blurs these units. The mass energy-absorption coefficient ${\mu }_{\mathrm{en}}/\rho$ weights the fraction of incident photon energy transferred to charged particles and retained after radiative losses, rather than simply counting all removals. Coherent scattering contributes attenuation with negligible energy transfer. A photon deflected by Compton scattering can carry much of the original energy away. One often writes ${\mu }_{\mathrm{en}}=(1-g){\mu }_{\mathrm{tr}}$, with $g$ the fraction of secondary charged-particle kinetic energy lost radiatively. Under charged-particle equilibrium, multiplying photon energy fluence by ${\mu }_{\mathrm{en}}/\rho$ gives the absorbed dose; that equilibrium condition matters near interfaces and in buildup regions.^[ref]

A spectrum-weighted water-equivalence ratio compares a specified material response with the corresponding water response after accounting for the radiation's energy distribution. Its definition must identify the interaction coefficient and the spectral weighting. An attenuation comparison and an energy-absorption comparison are different quantities.

For an energy-absorption comparison, let ${\Psi }_E(E)dE$ be the photon energy fluence in an energy interval, and write $a_j(E)=({\mu }_{\mathrm{en}}/\rho {)}_j(E)$ for material $j$. Define the coefficient-weighted response and its ratio bywith $A_w>0$. The same prescribed local photon energy fluence is used for both materials in this comparison. NIST distinguishes the mass energy-absorption coefficient from the mass attenuation coefficient and relates energy fluence to photon fluence through the additional photon-energy factor.^[ref]

The ratio is a weighted mean of the monoenergetic ratios $q(E)=a_m(E)/a_w(E)$, but its normalized weights areThus the weights depend on the water response as well as the incident spectrum. Averaging the ratios with energy-fluence weights alone generally gives a different result.

For an original two-line calculation, use the NIST water and PMMA energy-absorption data: at $30\mathrm{keV}$ the coefficients are $0.1557$ and $0.09645\mathrm{c}{\mathrm{m}}^2/g$ respectively; at $100\mathrm{keV}$ they are $0.02546$ and $0.02368\mathrm{c}{\mathrm{m}}^2/g$.^[ref] Equal energy fluences in the two lines giveEqual photon counts instead give energy-fluence weights proportional to $30$ and $100$, producing $Q_{\Psi }\approx 0.72904$. The different answers reflect different physical spectra, not a discrepancy in the tabulated coefficients.

An absorbed dose interpretation needs additional conditions such as charged-particle equilibrium. A finite object can also change the local spectrum through beam hardening and scattering. The ratio above therefore specifies a local coefficient-weighted comparison; it is not a universal conversion factor for every phantom size or irradiation geometry. A physical validation should characterize the local spectrum and detector energy response rather than assume that equal total fluence means equal spectral weighting.

A radiation physicist who coauthored NIST reference tables for X-ray and gamma ray interactions with John H. Hubbell. The mass energy-absorption data use his calculations to account for how much photon energy is retained after interaction processes. This supports radiation-energy deposition calculations alongside the separate mass attenuation coefficient used for beam transmission.^[ref]