Thermomolecular pressure ($p_T$)

Thermomolecular pressure is the temperature-dependent force per area transmitted through a thin liquid film between a solid and a substrate. For a repulsive ice-film interaction $p_T=A/(6\pi a^3)$, it can drive water through a porous material and support a load. Its thermodynamic relation to undercooling is the Clapeyron pressure relation for equal-density phases.

For equal solid and liquid mass densities, $d\mu =-sdT+dp/\rho$ and $s_l-s_s=L/T_m$ imply the displayed relation from equality of chemical potentials. $T_m$ must be absolute temperature. The phase pressures differ; this should not be confused with differentiating a coexistence curve along a common pressure.