Premelting

Premelting is the persistence of a liquid layer at a surface or interface below the bulk melting temperature. Molecular disjoining pressure and phase equilibrium can stabilize the film. Its hydraulic connection to a reservoir permits frost heave when water freezes onto the base of loaded ice.

Thermomolecular pressure is the temperature-dependent force per area transmitted through a thin liquid film between a solid and a substrate. For a repulsive ice-film interaction $p_T=A/(6\pi a^3)$, it can drive water through a porous material and support a load. Its thermodynamic relation to undercooling is the Clapeyron pressure relation for equal-density phases.

For equal solid and liquid mass densities, $d\mu =-sdT+dp/\rho$ and $s_l-s_s=L/T_m$ imply the displayed relation from equality of chemical potentials. $T_m$ must be absolute temperature. The phase pressures differ; this should not be confused with differentiating a coexistence curve along a common pressure.

Frost heave is displacement caused by segregated ice growth supplied by liquid flow, rather than solely by the expansion of water on freezing. A premelting film allows liquid access beneath the ice; thermomolecular pressure draws supply against viscous resistance and load.

A porous sheet of thickness $d$ and permeability of a porous medium $\Pi$ supplies a thin premelting film. The Darcy flow law equates water supply to ice growth for equal densities. With equal film and ice conductivities, negligible latent heat relative to the through-going conductive flux, and $a\ll h$, phase equilibrium gives $p_T=(\rho L\Delta T/T_m{)}^{3/4}(A/(6\pi h^3){)}^{1/4}$. The increasing gravitational load limits growth. A quasi-steady temperature field alone does not imply the negligible-latent-heat approximation.

For ${\eta }^{\prime }={\eta }^{-3/4}-\eta$, set $u={\eta }^{7/4}$ to get $u^{\prime }=(7/4)(1-u)$. The displayed solution approaches the stable equilibrium $\eta =1$. From the formal zero start it behaves as $(7\tau /4{)}^{4/7}$ at early times and $1-(4/7)e^{-7\tau /4}$ at late times. The zero-start asymptote is an intermediate reduced-model regime, since the physical thin-film approximation fails at vanishing ice thickness.

Combine the full quasi-steady Stefan condition above with $\delta T=T_m{p}_T/(\rho L)$, $a=(A/(6\pi p_T){)}^{1/3}$ and the Darcy flow law to obtain an implicit pressure-growth system. Even when latent heat is negligible, a conductivity ratio $K_s/K_l=r$ changes the leading molecular driving pressure by $r^{3/4}$. Thus a reduced equal-conductivity formula requires an explicit material and rate approximation.