For the pressure-density Hugoniot relation for a perfect gas, the change in specific entropy is , with the specific heat capacity at constant volume. Its derivative is
It is positive for a compressive normal shock wave with . For a weak shock with , integrating the leading term gives
Thus the entropy production is cubic in the small pressure jump, even though the mass density and temperature changes already appear at first order.
For equal weak shocks with individual pressure ratio and total ratio , entropy production in a perfect-gas shock gives
At fixed , this tends to zero as the compression is divided into increasingly many smaller weak shocks. A single finite normal shock wave instead gives the positive value . Gradual compression can consequently approach reversible isentropic flow while an abrupt compression generates finite entropy.
Work in the shock frame. The undisturbed upstream gas enters the stationary discontinuity at speed
while the downstream gas, which moves with the piston in the laboratory frame, leaves at
The Rankine-Hugoniot conditions for a perfect gas are
and
Eliminating the velocities between these equations gives the perfect-gas density jump
The mass and momentum equations also imply
so
Substitution of the density ratio into mass conservation, followed by this momentum relation, gives
Using the adiabatic sound speed therefore yields
Finally, eliminating from gives the piston-driven normal shock relation
For a compressive shock , the first boxed equation has : the shock propagates supersonically into the undisturbed gas, approaching the sound speed in the weak shock limit .
Put . Differentiating the expression in part (c) gives
For , the denominator is , so
Integrating from the unshocked state, where , proves the cubic entropy production in a perfect-gas shock:
The first-order and second-order terms vanish: a weak shock agrees with reversible compression through second order.
For equal weak shocks, , hence
Adding the individual increases in specific entropy gives the entropy production in successive weak shocks
By contrast, a single normal shock wave with the same total pressure ratio gives
Thus a single strong shock produces more entropy than the chain of sufficiently small weak shocks. At fixed , the chain approaches zero entropy production as , while the single-shock result stays positive. The gradual compression approaches reversible isentropic flow.
The Taylor series of the shock density ratio at is
For a reversible adiabatic process, , so the density ratio predicted by the ideal-gas adiabat is
Equations (1) and (2) agree through order . Thus a weak shock satisfies the adiabatic pressure-density relation with an error of order , which in particular establishes the requested accuracy through .