Ciro Santilli @cirosantilli  40

Just ignore the electron electron interactions.

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No closed form solution, but good approximation that can be calculated by hand with the Hartree-Fock method, see hartree-Fock method for the helium atom.

Bibliography:

This example covered for example at Video 1. "Term Symbols Example 1 by TMP Chem (2015)".

Carbon has electronic structure 1s2 2s2 2p2.

For term symbols we only care about unfilled layers, because in every filled layer the total z angular momentum is 0, as one electron necessarily cancels out each other:

So in this case, we only care about the 2 electrons in 2p2. Let's list out all possible ways in which the 2p2 electrons can be.

There are 3 p orbitals, with three different magnetic quantum numbers, each representing a different possible z quantum angular momentum.

We are going to distribute 2 electrons with 2 different spins across them. All the possible distributions that don't violate the Pauli exclusion principle are:

m_l  +1  0 -1  m_L  m_S
     u_ u_ __    1    1
     u_ __ u_    0    1
     __ u_ u_   -1    1
     d_ d_ __    1   -1
     d_ __ d_    0   -1
     __ d_ d_   -1   -1
     u_ d_ __    1    0
     d_ u_ __    1    0
     u_ __ d_    0    0
     d_ __ u_    0    0
     __ u_ d_   -1    0
     __ d_ u_   -1    0
     ud __ __    2    0
     __ ud __    0    0
     __ __ ud   -2    0

where:

For example, on the first line:we have:and so the sum of them has angular momentum $0+1\hslash =1\hslash$. So the value of $m_L$ is 1, we just omit the $\hslash$.

TODO now I don't understand the logic behind the next steps... I understand how to mechanically do them, but what do they mean? Can you determine the term symbol for individual microstates at all? Or do you have to group them to get the answer? Since there are multiple choices in some steps, it appears that you can't assign a specific term symbol to an individual microstate. And it has something to do with the Slater determinant. The previous lecture mentions it: www.youtube.com/watch?v=7_8n1TS-8Y0 more precisely youtu.be/7_8n1TS-8Y0?t=2268 about carbon.

youtu.be/DAgEmLWpYjs?t=2675 mentions that ${}^{3}D$ is not allowed because it would imply $L=2,S=1$, which would be a state uu __ __ which violates the Pauli exclusion principle, and so was not listed on our list of 15 states.

He then goes for ${}^{1}D$ and mentions:and so that corresponds to states on our list:Note that for some we had a two choices, so we just pick any one of them and tick them off off from the table, which now looks like:

Then for ${}^{3}P$ the choices are:so we have 9 possibilities for both together. We again verify that 9 such states are left matching those criteria, and tick them off, and so on.

For the $m_S$, we have two electrons with spin up. The angular momentum of each electron is $1/2\hslash$, and so given that we have two, the total is $1\hslash$, so again we omit $\hslash$ and $m_S$ is 1.

Bibliography:

Ciro Santilli is against all affirmative action, except for one: giving amazing free eduction to the poor.

Notably, Ciro is against university entry quotas.

Grew tremendously since the 1990's, likely linked to the Internet.

www.cbpp.org/wealth-concentration-has-been-rising-toward-early-20th-century-levels-2 shows historical for top 1% and 0.5% from 1920 to 2010.

TODO why is it so hard to find a proper cumulative distribution function-like curve? OMG. This appears to be also called a Lorenz curve.

Phenomena that produces photons in pairs as it passes through a certain type of crystal.

You can then detect one of the photons, and when you do you know that the other one is there as well and ready to be used. two photon interference experiment comes to mind, which is the basis of photonic quantum computer, where you need two photons to be produced at the exact same time to produce quantum entanglement.

The basic experiment for a photonic quantum computer.

Can be achieved in two ways it seems:

Animation of Hong-Ou-Mandel Effect on a silicon like structure by Quantum Light University of Sheffield (2014): www.youtube.com/watch?v=ld2r2IMt4vg No maths, but gives the result clear: the photons are always on the same side.

www.youtube.com/watch?v=6DxlkxA82FM COVID-19 Symposium: Entry of Coronavirus into Cells | Dr. Paul Bates

Interaction points:

Genes list: www.ncbi.nlm.nih.gov/nuccore/MN908947.3

Some are named after the encoded protein. Others that are not as clean are just orfXXX for open reading frame XXX.