Continuous spectrum (functional analysis) Updated +Created
Unlike the simple case of a matrix, in infinite dimensional vector spaces, the spectrum may be continuous.
The quintessential example of that is the spectrum of the position operator in quantum mechanics, in which any real number is a possible eigenvalue, since the particle may be found in any position. The associated eigenvectors are the corresponding Dirac delta functions.
Dirac delta function Updated +Created
The "0-width" pulse distribution that integrates to a step.
There's not way to describe it as a classical function, making it the most important example of a distribution.
Applications:
Distribution (mathematics) Updated +Created
Generalize function to allow adding some useful things which people wanted to be classical functions but which are not,
It therefore requires you to redefine and reprove all of calculus.
For this reason, most people are tempted to assume that all the hand wavy intuitive arguments undergrad teachers give are true and just move on with life. And they generally are.
One notable example where distributions pop up are the eigenvectors of the position operator in quantum mechanics, which are given by Dirac delta functions, which is most commonly rigorously defined in terms of distribution.
Distributions are also defined in a way that allows you to do calculus on them. Notably, you can define a derivative, and the derivative of the Heaviside step function is the Dirac delta function.
Momentum operator Updated +Created
One dimension in position representation:
In three dimensions In position representation, we define it by using the gradient, and so we see that
Video 1.
Position and Momentum from Wavefunctions by Faculty of Khan (2018)
Source. Proves in detail why the momentum operator is . The starting point is determining the time derivative of the expectation value of the position operator.
Position representation Updated +Created
A way to write the wavefunction such that the position operator is:i.e., a function that takes the wavefunction as input, and outputs another function:
If you believe that mathematicians took care of continuous spectrum for us and that everything just works, the most concrete and direct thing that this representation tells us is that:
the probability of finding a particle between and at time
equals:
Schrödinger picture Updated +Created
To better understand the discussion below, the best thing to do is to read it in parallel with the simplest possible example: Schrödinger picture example: quantum harmonic oscillator.
The state of a quantum system is a unit vector in a Hilbert space.
"Making a measurement" for an observable means applying a self-adjoint operator to the state, and after a measurement is done:
  • the state collapses to an eigenvector of the self adjoint operator
  • the result of the measurement is the eigenvalue of the self adjoint operator
  • the probability of a given result happening when the spectrum is discrete is proportional to the modulus of the projection on that eigenvector.
    For continuous spectra such as that of the position operator in most systems, e.g. Schrödinger equation for a free one dimensional particle, the projection on each individual eigenvalue is zero, i.e. the probability of one absolutely exact position is zero. To get a non-zero result, measurement has to be done on a continuous range of eigenvectors (e.g. for position: "is the particle present between x=0 and x=1?"), and you have to integrate the probability over the projection on a continuous range of eigenvalues.
    In such continuous cases, the probability collapses to an uniform distribution on the range after measurement.
    The continuous position operator case is well illustrated at: Video "Visualization of Quantum Physics (Quantum Mechanics) by udiprod (2017)"
Those last two rules are also known as the Born rule.
Self adjoint operators are chosen because they have the following key properties:
  • their eigenvalues form an orthonormal basis
  • they are diagonalizable
Perhaps the easiest case to understand this for is that of spin, which has only a finite number of eigenvalues. Although it is a shame that fully understanding that requires a relativistic quantum theory such as the Dirac equation.
The next steps are to look at simple 1D bound states such as particle in a box and quantum harmonic oscillator.
The solution to the Schrödinger equation for a free one dimensional particle is a bit harder since the possible energies do not make up a countable set.
This formulation was apparently called more precisely Dirac-von Neumann axioms, but it because so dominant we just call it "the" formulation.
Quantum Field Theory lecture notes by David Tong (2007) mentions that:
if you were to write the wavefunction in quantum field theory, it would be a functional, that is a function of every possible configuration of the field .
Uncertainty principle Updated +Created
The wave equation contains the entire state of a particle.
From mathematical formulation of quantum mechanics remember that the wave equation is a vector in Hilbert space.
And a single vector can be represented in many different ways in different basis, and two of those ways happen to be the position and the momentum representations.
More importantly, position and momentum are first and foremost operators associated with observables: the position operator and the momentum operator. And both of their eigenvalue sets form a basis of the Hilbert space according to the spectral theorem.
When you represent a wave equation as a function, you have to say what the variable of the function means. And depending on weather you say "it means position" or "it means momentum", the position and momentum operators will be written differently.
Furthermore, the position and momentum representations are equivalent: one is the Fourier transform of the other: position and momentum space. Remember that notably we can always take the Fourier transform of a function in due to Carleson's theorem.
Then the uncertainty principle follows immediately from a general property of the Fourier transform: en.wikipedia.org/w/index.php?title=Fourier_transform&oldid=961707157#Uncertainty_principle
In precise terms, the uncertainty principle talks about the standard deviation of two measures.
We can visualize the uncertainty principle more intuitively by thinking of a wave function that is a real flat top bump function with a flat top in 1D. We can then change the width of the support, but when we do that, the top goes higher to keep probability equal to 1. The momentum is 0 everywhere, except in the edges of the support. Then:
  • to localize the wave in space at position 0 to reduce the space uncertainty, we have to reduce the support. However, doing so makes the momentum variation on the edges more and more important, as the slope will go up and down faster (higher top, and less x space for descent), leading to a larger variance (note that average momentum is still 0, due to to symmetry of the bump function)
  • to localize the momentum as much as possible at 0, we can make the support wider and wider. This makes the bumps at the edges smaller and smaller. However, this also obviously delocalises the wave function more and more, increasing the variance of x