In this solution of the Schrödinger equation, by the uncertainty principle, position is completely unknown (the particle could be anywhere in space), and momentum (and therefore, energy) is perfectly known.
The plane wave function appears for example in the solution of the Schrödinger equation for a free one dimensional particle. This makes sense, because when solving with the time-independent Schrödinger equation, we do separation of variable on fixed energy levels explicitly, and the plane wave solutions are exactly fixed energy level ones.
Experiments explained:
- via the Schrödinger equation solution for the hydrogen atom it predicts:
- spectral line basic lines, plus Zeeman effect
- Schrödinger equation solution for the helium atom: perturbative solutions give good approximations to the energy levels
- double-slit experiment: I think we have a closed solution for the max and min probabilities on the measurement wall, and they match experiments
Experiments not explained: those that the Dirac equation explains like:
- fine structure
- spontaneous emission coefficients
To get some intuition on the equation on the consequences of the equation, have a look at:
The easiest to understand case of the equation which you must have in mind initially that of the Schrödinger equation for a free one dimensional particle.
Then, with that in mind, the general form of the Schrödinger equation is:where:
Equation 1.
Schrodinger equation
. - is the reduced Planck constant
- is the wave function
- is the time
- is a linear operator called the Hamiltonian. It takes as input a function , and returns another function. This plays a role analogous to the Hamiltonian in classical mechanics: determining it determines what the physical system looks like, and how the system evolves in time, because we can just plug it into the equation and solve it. It basically encodes the total energy and forces of the system.
The argument of could be anything, e.g.:Note however that there is always a single magical time variable. This is needed in particular because there is a time partial derivative in the equation, so there must be a corresponding time variable in the function. This makes the equation explicitly non-relativistic.
- we could have preferred polar coordinates instead of linear ones if the potential were symmetric around a point
- we could have more than one particle, e.g. solutions of the Schrodinger equation for two electrons, which would have e.g. and for different particles. No matter how many particles there are, we have just a single , we just add more arguments to it.
- we could have even more generalized coordinates. This is much in the spirit of Hamiltonian mechanics or generalized coordinates
The general Schrödinger equation can be broken up into a trivial time-dependent and a time-independent Schrödinger equation by separation of variables. So in practice, all we need to solve is the slightly simpler time-independent Schrödinger equation, and the full equation comes out as a result.
To better understand the discussion below, the best thing to do is to read it in parallel with the simplest possible example: Schrödinger picture example: quantum harmonic oscillator.
The state of a quantum system is a unit vector in a Hilbert space.
"Making a measurement" for an observable means applying a self-adjoint operator to the state, and after a measurement is done:Those last two rules are also known as the Born rule.
- the state collapses to an eigenvector of the self adjoint operator
- the result of the measurement is the eigenvalue of the self adjoint operator
- the probability of a given result happening when the spectrum is discrete is proportional to the modulus of the projection on that eigenvector.For continuous spectra such as that of the position operator in most systems, e.g. Schrödinger equation for a free one dimensional particle, the projection on each individual eigenvalue is zero, i.e. the probability of one absolutely exact position is zero. To get a non-zero result, measurement has to be done on a continuous range of eigenvectors (e.g. for position: "is the particle present between x=0 and x=1?"), and you have to integrate the probability over the projection on a continuous range of eigenvalues.In such continuous cases, the probability collapses to an uniform distribution on the range after measurement.The continuous position operator case is well illustrated at: Video "Visualization of Quantum Physics (Quantum Mechanics) by udiprod (2017)"
Self adjoint operators are chosen because they have the following key properties:
- their eigenvalues form an orthonormal basis
- they are diagonalizable
Perhaps the easiest case to understand this for is that of spin, which has only a finite number of eigenvalues. Although it is a shame that fully understanding that requires a relativistic quantum theory such as the Dirac equation.
The next steps are to look at simple 1D bound states such as particle in a box and quantum harmonic oscillator.
This naturally generalizes to Schrödinger equation solution for the hydrogen atom.
The solution to the Schrödinger equation for a free one dimensional particle is a bit harder since the possible energies do not make up a countable set.
This formulation was apparently called more precisely Dirac-von Neumann axioms, but it because so dominant we just call it "the" formulation.
Quantum Field Theory lecture notes by David Tong (2007) mentions that:
if you were to write the wavefunction in quantum field theory, it would be a functional, that is a function of every possible configuration of the field .