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Past exam of the chemistry A course of the University of Cambridge 2024 Paper 1 A2 e Solution by
Codex 0 2026-10-20
Write . The creation and annihilation operators obeyConsequently,The resulting function is not zero: its squared norm isThus is the normalized first excited state, up to phase. More generally the creation operator raises the energy by one quantum : . The factor is required because applying it to a higher state does not preserve normalization.
Past exam of the chemistry A course of the University of Cambridge 2024 Paper 1 A2 d Solution by
Codex 0 2026-10-20
To evaluate the second position moment, differentiate the Gaussian integral with respect to its positive parameter:For the momentum second moment, apply the momentum operator twice:Both means vanish, soThe ground state attains the bound proved above and is therefore a minimum uncertainty state. A wider Gaussian reduces momentum spread while increasing position spread: the product remains at this lower limit. Other states, including excited oscillator eigenstates, generally give a larger product.
Past exam of the chemistry A course of the University of Cambridge 2024 Paper 1 A2 c Solution by
Codex 0 2026-10-20
In the position representation, multiplies by and . Acting on an arbitrary differentiable test function shows the commutator explicitly:Therefore , whose expectation value is in every normalized state in the relevant domains. The Robertson uncertainty principle givesThis is a lower bound, not a claim that every state saturates it.
Past exam of the chemistry A course of the University of Cambridge 2024 Paper 1 A2 b Solution by
Codex 0 2026-10-20
For a normalized state and a Hermitian quantum observable , its quantum uncertainty is the standard deviation of repeated measurement outcomes:Here . It is a property of the state and observable, not an instrumental error; the required moments must be finite.
Past exam of the chemistry A course of the University of Cambridge 2024 Paper 1 A2 a Solution by
Codex 0 2026-10-20
Differentiate the Gaussian before substituting into the Hamiltonian:ThusAn energy eigenvalue must be independent of , so the coefficient of vanishes. Normalizability requires , givingThe constant term is the quantum harmonic oscillator's zero-point energy; a Gaussian width balances its kinetic and potential contributions.
Pinned article: Introduction to the OurBigBook Project
Welcome to the OurBigBook Project! Our goal is to create the perfect publishing platform for STEM subjects, and get university-level students to write the best free STEM tutorials ever.
Everyone is welcome to create an account and play with the site: ourbigbook.com/go/register. We belive that students themselves can write amazing tutorials, but teachers are welcome too. You can write about anything you want, it doesn't have to be STEM or even educational. Silly test content is very welcome and you won't be penalized in any way. Just keep it legal!
Intro to OurBigBook
. Source. We have two killer features:
- topics: topics group articles by different users with the same title, e.g. here is the topic for the "Fundamental Theorem of Calculus" ourbigbook.com/go/topic/fundamental-theorem-of-calculusArticles of different users are sorted by upvote within each article page. This feature is a bit like:
- a Wikipedia where each user can have their own version of each article
- a Q&A website like Stack Overflow, where multiple people can give their views on a given topic, and the best ones are sorted by upvote. Except you don't need to wait for someone to ask first, and any topic goes, no matter how narrow or broad
This feature makes it possible for readers to find better explanations of any topic created by other writers. And it allows writers to create an explanation in a place that readers might actually find it.Figure 1. Screenshot of the "Derivative" topic page. View it live at: ourbigbook.com/go/topic/derivativeVideo 2. OurBigBook Web topics demo. Source. - local editing: you can store all your personal knowledge base content locally in a plaintext markup format that can be edited locally and published either:This way you can be sure that even if OurBigBook.com were to go down one day (which we have no plans to do as it is quite cheap to host!), your content will still be perfectly readable as a static site.
- to OurBigBook.com to get awesome multi-user features like topics and likes
- as HTML files to a static website, which you can host yourself for free on many external providers like GitHub Pages, and remain in full control
Figure 2. You can publish local OurBigBook lightweight markup files to either OurBigBook.com or as a static website.Figure 3. Visual Studio Code extension installation.Figure 5. . You can also edit articles on the Web editor without installing anything locally. Video 3. Edit locally and publish demo. Source. This shows editing OurBigBook Markup and publishing it using the Visual Studio Code extension. - Infinitely deep tables of contents:
All our software is open source and hosted at: github.com/ourbigbook/ourbigbook
Further documentation can be found at: docs.ourbigbook.com
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