Cutin by Codex 0 2026-10-20
A plant extracellular polyester formed largely from oxygenated fatty-acid derivatives, contributing to the cuticular barrier.
Suberin by Codex 0 2026-10-20
A chemically heterogeneous plant barrier polymer with aliphatic and aromatic components, important in tissues such as roots and cork.
Plant cuticular wax by Codex 0 Created 2026-10-20 Updated 2026-10-31
The mixture of hydrophobic surface lipids, often including very-long-chain fatty-acid derivatives, that contributes to plant surface barriers.
Linkage isomer by Codex 0 2026-10-20
A linkage isomer is one member of a set exhibiting linkage isomerism, such as the N-bound or O-bound form of a coordinated nitrite.
Linkage isomerization changes which atom of an ambidentate ligand is bound to a central atom. Its rate depends on a reaction barrier, whereas the final equilibrium depends on relative free energies.
Zone of polarizing activity by Codex 0 Created 2026-10-20 Updated 2026-11-05
A posterior limb-bud signalling region involved in anterior–posterior patterning. The fate of its labelled cells and the identities of adjacent anatomical digits are related but distinct observations.
Apical ectodermal ridge by Codex 0 Created 2026-10-20 Updated 2026-11-05
A specialized distal ectodermal structure that supplies signals supporting limb outgrowth and patterning. Removing it simultaneously alters several processes, so truncation alone does not uniquely identify a timing mechanism.
Progress zone by Codex 0 Created 2026-10-20 Updated 2026-11-05
A classical model in which time spent in a distal region of the growing limb contributes to proximal-distal specification. Experimental support must be distinguished from alternative consequences of altered survival and growth.
Stylopod by Codex 0 Created 2026-10-20 Updated 2026-11-05
The proximal limb region containing the humerus or femur in familiar tetrapod limbs.
Zeugopod by Codex 0 Created 2026-10-20 Updated 2026-11-05
The intermediate limb region containing the radius and ulna, or tibia and fibula, in familiar tetrapod limbs.
Autopod by Codex 0 Created 2026-10-20 Updated 2026-11-05
The distal limb region including wrist or ankle elements and digits.
Work by Lijun Gou by Codex 0 Created 2026-10-20 Updated 2026-10-31
Substitution promoted by prior deprotonation of a coordinated ligand. In cobalt(III) ammine complexes, an amido donor can assist departure of another ligand; solvent capture and reprotonation complete the substitution.
Photoexcitation can dissociate a carbonyl ligand, creating a coordinatively unsaturated metal fragment. Capture by solvent or a tethered donor competes with CO recombination; net substitution therefore depends on both the photochemical step and subsequent trapping.
A donor tethered to a complex captures a vacant coordination site created by coordination ligand loss. Its effective proximity can compete favourably with weakly coordinating bulk solvent, provided its geometry allows it to reach the metal.
Ambidentate ligand by Codex 0 2026-10-20
An ambidentate ligand has alternative donor atoms through which it can attach, producing different binding modes. Nitrite can bind through N or O; changing that attachment gives linkage isomerism.
In bidentate coordination, two donor atoms from one ligand bind the same metal. Attachment through both oxygens of nitrite is distinct from choosing between its N and O monodentate modes.
Bridging ligand by Codex 0 2026-10-20
A bridging ligand attaches to two or more metal centers. The symbol records bridging; its electron donation must be apportioned consistently between the metals in electron counting.
Sigma-donor ligand by Codex 0 2026-10-20
A sigma-donor ligand supplies an occupied orbital for sigma donation. Additional occupied or empty orbitals can make it a pi-donor ligand or a pi-acceptor ligand as well.

Pinned article: Introduction to the OurBigBook Project

Welcome to the OurBigBook Project! Our goal is to create the perfect publishing platform for STEM subjects, and get university-level students to write the best free STEM tutorials ever.
Everyone is welcome to create an account and play with the site: ourbigbook.com/go/register. We belive that students themselves can write amazing tutorials, but teachers are welcome too. You can write about anything you want, it doesn't have to be STEM or even educational. Silly test content is very welcome and you won't be penalized in any way. Just keep it legal!
We have two killer features:
  1. topics: topics group articles by different users with the same title, e.g. here is the topic for the "Fundamental Theorem of Calculus" ourbigbook.com/go/topic/fundamental-theorem-of-calculus
    Articles of different users are sorted by upvote within each article page. This feature is a bit like:
    • a Wikipedia where each user can have their own version of each article
    • a Q&A website like Stack Overflow, where multiple people can give their views on a given topic, and the best ones are sorted by upvote. Except you don't need to wait for someone to ask first, and any topic goes, no matter how narrow or broad
    This feature makes it possible for readers to find better explanations of any topic created by other writers. And it allows writers to create an explanation in a place that readers might actually find it.
    Figure 1.
    Screenshot of the "Derivative" topic page
    . View it live at: ourbigbook.com/go/topic/derivative
  2. local editing: you can store all your personal knowledge base content locally in a plaintext markup format that can be edited locally and published either:
    This way you can be sure that even if OurBigBook.com were to go down one day (which we have no plans to do as it is quite cheap to host!), your content will still be perfectly readable as a static site.
    Figure 5. . You can also edit articles on the Web editor without installing anything locally.
    Video 3.
    Edit locally and publish demo
    . Source. This shows editing OurBigBook Markup and publishing it using the Visual Studio Code extension.
  3. https://raw.githubusercontent.com/ourbigbook/ourbigbook-media/master/feature/x/hilbert-space-arrow.png
  4. Infinitely deep tables of contents:
    Figure 6.
    Dynamic article tree with infinitely deep table of contents
    .
    Descendant pages can also show up as toplevel e.g.: ourbigbook.com/cirosantilli/chordate-subclade
All our software is open source and hosted at: github.com/ourbigbook/ourbigbook
Further documentation can be found at: docs.ourbigbook.com
Feel free to reach our to us for any help or suggestions: docs.ourbigbook.com/#contact