Electro-osmosis

Electro-osmosis is fluid motion driven by an applied electric field acting on mobile electric charge near a surface. A charged interface attracts a diffuse population of counterions in an electric double layer. A field component tangent to the interface exerts a force density ${\rho }_e\mathbf{E}$ on that mobile charge; momentum transfer to the surrounding solvent drives flow opposed by viscous stress. In a capillary electrophoresis measurement, this flow advects the sample as well as its electrical drift relative to the fluid. Locally, the measured axial velocity is $v_{\mathrm{observed}}=u_{\mathrm{eo}}+{\mu }_{\mathrm{ep}}E$, where $u_{\mathrm{eo}}$ is the electroosmotic fluid velocity and ${\mu }_{\mathrm{ep}}$ is the electrophoretic mobility. ^[ref]