Pycnometer density measurement 2026-10-14
A pycnometer makes the distinction between mass and mass density experimentally tangible. NIST's 1994 report describes a glass vessel with filling capillaries, wire plugs and a covered overflow bowl in a controlled water bath. The operators soaked a pure-water filling to establish the bath temperature, dried the outside, then left it overnight in the balance enclosure to reach thermal equilibrium before weighing. Empty and full force-restoration balance readings, together with known water mass density, calibrated its capacity at the bath temperature. A tin-oxide coating suppressed stray electric charge; an electrometer detected none during use. The authors distinguish bath and weighing temperatures and correct for buoyancy and changes of displacement volume. Capacity and water-reference uncertainties carry into later liquid mass density determinations. Their pycnometer data were not yet analyzed, so this account provides no measured density or achieved precision.[ref]
The Electronic Balance and Some Gravimetric Applications (The Density of Solids and Liquids, Pycnometry and Mass) by Randall M. Schoonover and others. The Electronic Balance and Some Gravimetric Applications (The Density of Solids and Liquids, Pycnometry and Mass), NISTIR 5375, printed pp. 313–316, “Pycnometer Calibration”, Figure 5 and “Pycnometer Application”; p. 315 states that pycnometer data had not yet been analyzed
The ideal accounting behind this measurement calibration can be derived without numerical observations. Let denote corrected masses of the empty vessel, water-filled vessel and sample-filled vessel. At the same filling temperature, with known reference water mass density and reproducibly filled volume ,The empty-vessel subtraction removes vessel mass; the water filling sets volume. Doubling for the same uniform sample doubles the sample mass increment but preserves . Uncorrected balance indications, trapped bubbles, incomplete filling or unequal filling temperatures break the simple identification with corrected mass and a common . This explains why replication is a statement about comparable states rather than arbitrary instrument readings.
Radiation-pressure laser power measurement 2026-10-14
A 2013 experiment by Paul A. Williams and collaborators mounted a 25-mm dielectric mirror on a commercial force-restoration balance. Removing its pan-weight compensation spring allowed horizontal force sensing with a horizontal laser path. They measured mirror optical reflectance and varied incidence from about to . A 1071-nm laser, capable of 530 W, was switched at 0.1 Hz. Digitized mass-equivalent readings were converted to force using ; quadrature demodulation isolated the switched signal from drift. [ref]
Measurement calibration used a 20-g mass, with checks down to 1 mg. The optical forces lay below that checked range, limiting the accuracy claim. An angle scan tested the predicted cosine dependence at fixed intercepted power. Replacing the mirror with a carbon nanotube coated absorber increased absorbed power while reducing the predicted optical force; no modulation peak was detected. This bounded gas-heating artifacts under those conditions, rather than proving their universal absence. The fitted slope was about 7% below . Inferring laser power requires calibrated force, optical reflectance, radiometric absorptance and angle of incidence, with measurement uncertainty for each. [ref]