A pycnometer makes the distinction between mass and mass density experimentally tangible. NIST's 1994 report describes a glass vessel with filling capillaries, wire plugs and a covered overflow bowl in a controlled water bath. The operators soaked a pure-water filling to establish the bath temperature, dried the outside, then left it overnight in the balance enclosure to reach thermal equilibrium before weighing. Empty and full force-restoration balance readings, together with known water mass density, calibrated its capacity at the bath temperature. A tin-oxide coating suppressed stray electric charge; an electrometer detected none during use. The authors distinguish bath and weighing temperatures and correct for buoyancy and changes of displacement volume. Capacity and water-reference uncertainties carry into later liquid mass density determinations. Their pycnometer data were not yet analyzed, so this account provides no measured density or achieved precision.[ref]
The ideal accounting behind this measurement calibration can be derived without numerical observations. Let denote corrected masses of the empty vessel, water-filled vessel and sample-filled vessel. At the same filling temperature, with known reference water mass density and reproducibly filled volume ,
The empty-vessel subtraction removes vessel mass; the water filling sets volume. Doubling for the same uniform sample doubles the sample mass increment but preserves . Uncorrected balance indications, trapped bubbles, incomplete filling or unequal filling temperatures break the simple identification with corrected mass and a common . This explains why replication is a statement about comparable states rather than arbitrary instrument readings.
A 2013 experiment by Paul A. Williams and collaborators mounted a 25-mm dielectric mirror on a commercial force-restoration balance. Removing its pan-weight compensation spring allowed horizontal force sensing with a horizontal laser path. They measured mirror optical reflectance and varied incidence from about to . A 1071-nm laser, capable of 530 W, was switched at 0.1 Hz. Digitized mass-equivalent readings were converted to force using ; quadrature demodulation isolated the switched signal from drift. [ref]
Measurement calibration used a 20-g mass, with checks down to 1 mg. The optical forces lay below that checked range, limiting the accuracy claim. An angle scan tested the predicted cosine dependence at fixed intercepted power. Replacing the mirror with a carbon nanotube coated absorber increased absorbed power while reducing the predicted optical force; no modulation peak was detected. This bounded gas-heating artifacts under those conditions, rather than proving their universal absence. The fitted slope was about 7% below . Inferring laser power requires calibrated force, optical reflectance, radiometric absorptance and angle of incidence, with measurement uncertainty for each. [ref]