For a bounded smooth domain and , let , normalized by . For an interior point , Green's third identity is
It represents the function through its volume PDE source term, boundary values and outward normal derivative. For a harmonic function the volume term vanishes, so boundary data alone reconstruct the interior.
To derive it, apply Green's second identity on . The inner sphere has the outward normal of the punctured domain, pointing toward . Its singular fundamental solution term tends to as , giving the stated signs. Replacing by the Dirichlet Green function makes its boundary value zero and leaves the Poisson kernel multiplying the boundary values of . Thus the identity connects Green functions, boundary integral representations and Dirichlet problems.
For smooth functions on a region ,
If is constant on the boundary and is a regular harmonic function throughout a volume, the divergence theorem applied to gives . The constant boundary value factors out; a second application of the divergence theorem makes the remaining flux . This requires enough regularity to use Green's first identity over the entire volume.
Although is harmonic away from the origin in three dimensions, it is not a regular harmonic function on a ball containing the origin. Its gradient is , so the displayed improper volume integral follows by canceling the in the spherical volume element. On the annulus , Green's first identity gives outer boundary contribution and inner contribution , recovering the same limit. Its global Laplacian contains a Dirac delta distribution, so the regular-harmonic gradient-pairing theorem is inapplicable.

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Green's identities are two important equations in vector calculus that relate the behavior of functions and their gradients over a region in space. They are particularly useful in physics and engineering for problems involving potential theory, fluid dynamics, and electrostatics. Green's identities can be viewed as forms of the divergence theorem and integration by parts.