Inverse temperature 2026-10-05
Inverse temperature is , where is the Boltzmann constant and is the absolute temperature. A canonical ensemble weights an energy by its Boltzmann factor . Calling couplings dimensionless means absorbing this factor into their energy coefficients. The alternative convention makes inverse temperature ; physical and dimensionless couplings must not be mixed.
In a thermal Euclidean worldline path integral with , is also the circumference of the imaginary-time circle.
Take the couplings in the Hamiltonian to include inverse temperature, so the Boltzmann factor is . If physical energies are used instead, first replace by their products with . Split the on-site term equally between its two bonds. For spin states the spin-chain transfer matrix has entries
Using the specified coupling coordinates, in the order this is
For example, and . This is the nearest-neighbour Blume–Emery–Griffiths model with an additive constant and the paper's sign convention for .
Summing the periodic spin chain gives the partition function . For finite real couplings all entries of are strictly positive; the Perron–Frobenius theorem gives a unique positive dominant eigenvalue with for . Since is a symmetric matrix, all its eigenvalues are real. Thus in the thermodynamic limit,
The positivity condition is stronger and more useful than mere ordering by signed value: subdominant eigenvalues can be negative. Also, the printed strict ordering between the other two is not guaranteed for all couplings. For instance, makes the positive constant matrix with two equal zero eigenvalues. Degeneracy there does not affect the largest-eigenvalue limit; no explicit generic eigenvalues are needed.
For spin magnetization, introduce a dimensionless field through , or insert into the trace. Then
where is a normalized eigenvector of the largest eigenvalue and . Spin inversion symmetry gives , since the positive eigenvector of the largest eigenvalue is unique. Therefore
at zero field, both at finite and in the finite-coupling thermodynamic limit. The finite- result follows directly by pairing each configuration with its spin-reversed partner. Eigenvalues at a single fixed field do not determine a general observable: a field derivative of the largest eigenvalue, or its eigenvector, is required. Positivity and the real analytic dependence on the couplings exclude a finite-temperature spontaneous symmetry breaking transition in this one-dimensional finite-range chain; singular zero-temperature coupling limits require separate treatment.
For even , spin decimation on alternate sites sums the middle spin of each two-bond segment, hence the coarse spin-chain transfer matrix is . Define
Direct multiplication gives . Matching its entry ratios to the original parameterization yields the spin-1 chain decimation recursion
The remaining overall positive factor is absorbed into . Keeping that factor preserves the free energy as well as normalized spin probabilities. Indeed , exactly; on an odd ring an unmatched boundary segment needs separate handling rather than assuming a uniform two-site block decomposition.
For , the quantum harmonic oscillator has energies , , in units . For positive inverse temperature , taking the trace in the energy basis and summing a geometric series gives
This is the thermal partition function of a quantum harmonic oscillator, including its zero-point energy. The assumptions ensure convergence; at the free particle on the noncompact line instead has an infinite spatial-volume factor.
For a quantum harmonic oscillator with , and inverse temperature , the canonical partition function is . The geometric series gives the displayed formula. Keeping the zero-point energy is essential to its prefactor.