For a nondegenerate two-dimensional electron gas, the two quadratic momentum terms supply each by the equipartition theorem. There is no lattice restoring potential energy for a free electron. Thus
On cooling below the Fermi temperature, the Pauli exclusion principle restricts the thermally active electrons to within approximately of the Fermi energy. The linear low-temperature heat capacity of a two-dimensional Fermi gas is
The heat capacity therefore decreases from its classical value as quantum degeneracy becomes important. The particle number of electrons and sample area are held fixed when differentiating the internal energy.
The chemical potential is the change in internal energy when one particle is added at fixed entropy and volume:
Equivalently, for the Helmholtz free energy.
Let a microstate have energy and particle number . Maximizing the Gibbs entropy subject to normalization and fixed mean values of and is the maximum-entropy derivation of equilibrium ensembles. With Lagrange multipliers , , and , vary
The stationarity equation is . Normalization therefore gives the grand canonical ensemble
Here is the grand canonical partition function and is the Boltzmann constant.
For one fermionic quantum state of energy , the Pauli exclusion principle permits occupation numbers only . Its two grand-canonical weights are and , so its mean occupation is the Fermi-Dirac distribution
For a free nonrelativistic particle, . In a region of area , the number of wave-vector states in the annulus from to , including the two spin angular momentum states, is
Since , the two-dimensional free-electron density of states is constant:
We now use units in which , as in the question. At zero temperature, the Fermi-Dirac distribution is a step function, and hence
At positive temperature the same fixed particle number satisfies the exact relation
Thus
This is the low-temperature particle-number cancellation for constant density of states. Therefore, for , the mean number of particles in the energy interval is
Finally, compare the internal energy with its zero-temperature value. The thermally excited particles above and holes below have equal leading particle numbers, so their terms proportional to cancel. With ,
where the integral follows from the fermion-to-boson thermal integral ratio. Differentiation gives the linear low-temperature heat capacity of a two-dimensional Fermi gas:
The requested power law is therefore linear in , with exponent one.