The chemical potential is the change in internal energy when one particle is added at fixed entropy and volume:
Equivalently, for the Helmholtz free energy.
Let a microstate have energy and particle number . Maximizing the Gibbs entropy subject to normalization and fixed mean values of and is the maximum-entropy derivation of equilibrium ensembles. With Lagrange multipliers , , and , vary
The stationarity equation is . Normalization therefore gives the grand canonical ensemble
Here is the grand canonical partition function and is the Boltzmann constant.
For one fermionic quantum state of energy , the Pauli exclusion principle permits occupation numbers only . Its two grand-canonical weights are and , so its mean occupation is the Fermi-Dirac distribution
For a free nonrelativistic particle, . In a region of area , the number of wave-vector states in the annulus from to , including the two spin angular momentum states, is
Since , the two-dimensional free-electron density of states is constant:
We now use units in which , as in the question. At zero temperature, the Fermi-Dirac distribution is a step function, and hence
At positive temperature the same fixed particle number satisfies the exact relation
Thus
This is the low-temperature particle-number cancellation for constant density of states. Therefore, for , the mean number of particles in the energy interval is
Finally, compare the internal energy with its zero-temperature value. The thermally excited particles above and holes below have equal leading particle numbers, so their terms proportional to cancel. With ,
where the integral follows from the fermion-to-boson thermal integral ratio. Differentiation gives the linear low-temperature heat capacity of a two-dimensional Fermi gas:
The requested power law is therefore linear in , with exponent one.
Keep the chemical potential at its zero-temperature value and put . Away from ,
Consequently
where
The bracket is an odd function localized to . When , extending the lower limit to makes the integral vanish exactly. The omitted tail is exponentially small; indeed direct integration gives
This is the low-temperature particle-number cancellation for constant density of states.
For the energy,
At low temperature the first term is exponentially small. In the second, extend the lower limit to and set :
The remaining integral is a finite positive constant, proving the quadratic low-temperature energy correction for constant density of states: