The mean first-passage time obeys the backward equation
For , direct integration gives
In particular,
This increases monotonically with drift away from the target, so the constrained optimum is
Expanding the exponential at zero drift yields
The adsorption mechanism is uniform along the two vertical sides, and evolves independently of . Consequently the mean first-passage time depends only on the initial -coordinate. Its Kolmogorov backward equation for is
The forward partially absorbing boundary condition for a diffusion is . The boundary term in the adjoint relation is
because the diffusion coefficient is one. It vanishes for every admissible precisely when
For , the two Robin boundary conditions are therefore
The general solution of the ordinary differential equation is
The right condition gives , and the left gives . At the prescribed initial position,
Each addition starts a new statistically identical waiting episode at zero gap. Thus the addition rate is the reciprocal of a mean first-passage time, not the reciprocal of the mean gap:
This can also be derived without the steady density. If is the mean time to reach starting at gap , its backward Smoluchowski equation is
The first boundary is reflecting and the second absorbing. An integrating factor gives , whence
At weak force, is the time for a freely diffusing wall to move a monomer length, with reflection at the tip. At strong force, opening the gap requires work , with Boltzmann distribution suppression . The drift establishes a near-tip thermal length and a diffusion time ; consequently
The exponentially long wait explains why the growth slows. There is no additional chemical waiting time in the imposed absorbing-threshold model; such a time would be needed to describe the separate reaction-limited polymerization Brownian ratchet regime.
Smoluchowski equation 2026-10-18
For overdamped Brownian motion at uniform temperature in a potential energy , constant diffusion coefficient gives the displayed Fokker-Planck equation, with . The probability current is . Zero current recovers the Boltzmann distribution; absorbing boundaries instead permit transport and mean first-passage times. This diffusion equation should be distinguished from the similarly named coagulation equation.