Past exam of the mathematics course of the University of Cambridge 2023 iii Paper 356 1 b Solution 2026-09-28
Past exam of the mathematics course of the University of Cambridge 2024 iii Paper 356 2 c Solution 2026-09-28
The adsorption mechanism is uniform along the two vertical sides, and evolves independently of . Consequently the mean first-passage time depends only on the initial -coordinate. Its Kolmogorov backward equation for is
The forward partially absorbing boundary condition for a diffusion is . The boundary term in the adjoint relation isbecause the diffusion coefficient is one. It vanishes for every admissible precisely whenFor , the two Robin boundary conditions are therefore
The general solution of the ordinary differential equation isThe right condition gives , and the left gives . At the prescribed initial position,
Each addition starts a new statistically identical waiting episode at zero gap. Thus the addition rate is the reciprocal of a mean first-passage time, not the reciprocal of the mean gap:This can also be derived without the steady density. If is the mean time to reach starting at gap , its backward Smoluchowski equation isThe first boundary is reflecting and the second absorbing. An integrating factor gives , whenceAt weak force, is the time for a freely diffusing wall to move a monomer length, with reflection at the tip. At strong force, opening the gap requires work , with Boltzmann distribution suppression . The drift establishes a near-tip thermal length and a diffusion time ; consequentlyThe exponentially long wait explains why the growth slows. There is no additional chemical waiting time in the imposed absorbing-threshold model; such a time would be needed to describe the separate reaction-limited polymerization Brownian ratchet regime.
Smoluchowski equation 2026-10-18
For overdamped Brownian motion at uniform temperature in a potential energy , constant diffusion coefficient gives the displayed Fokker-Planck equation, with . The probability current is . Zero current recovers the Boltzmann distribution; absorbing boundaries instead permit transport and mean first-passage times. This diffusion equation should be distinguished from the similarly named coagulation equation.