Past exam of the advanced quantum physics course of the University of Cambridge / 2012 / Paper 1 / 2

The WKB approximation, also called JWKB, describes a short local de Broglie wavelength in a slowly varying potential energy. For $p(x)=\sqrt{2m[E-V(x)]}$ in a classically allowed region, its two local waves areThe phase follows the classical momentum; its amplitude varies to conserve probability current. In a forbidden region, putting $\kappa (x)=\sqrt{2m[V(x)-E]}$ gives $\psi \simeq {\kappa }^{-1/2}[C{e}^{{\int }^x\kappa /\hslash }+D{e}^{-{\int }^x\kappa /\hslash }]$, with boundary conditions selecting the physical combination.

The WKB validity condition is $\hslash |p^{\prime }|/p^2\ll 1$, with the analogous condition on $\kappa$. It fails at a turning point where $E=V$. For a simple turning point, locally linearizing V yields an Airy function; matching fixes the relative amplitudes and a $\pi /4$ phase. Two such turning points give the two-turning-point WKB quantization conditionFor an opaque barrier, the WKB tunnelling exponent instead givesThe factor two distinguishes probability from amplitude. Matching determines the prefactor; the exponential alone is not accurate near the barrier top. These formulas connect bound state energy eigenvalues and quantum tunnelling to classical actions. ^[ref]

For a point, stationary proton, the leading hydrogen fine structure comes from three order-$1/c^2$ contributions to the nonrelativistic electron Hamiltonian:These are the relativistic kinetic-energy correction, spin-orbit interaction and Darwin term. The spin-orbit coefficient includes the Thomas precession factor of one half; $⟨\mathbf{L}\cdot \mathbf{S}⟩={\hslash }^2[j(j+1)-l(l+1)-3/4]/2$. The Coulomb Darwin contribution is a positive contact term, relevant for S states. These corrections distinguish total angular momentum $j=l\pm 1/2$, while leaving magnetic substates degenerate without an external field.

Writing ${\alpha }_{\mathrm{fs}}=e^2/(4\pi {ϵ}_0\hslash c)$, the combined hydrogen fine-structure correction isThus the splitting is of order ${\alpha }_{\mathrm{fs}}^2$ times the principal binding energy. In the $n=2$ shell, $2S_{1/2}$ and $2P_{1/2}$ remain degenerate in this approximation, while $2P_{3/2}$ is higher by $m_e{c}^2{\alpha }_{\mathrm{fs}}^4/32$. The Lamb shift lifts the remaining S–P degeneracy; hyperfine structure is a separate nuclear-spin effect. Neither is part of the displayed correction. Nuclear recoil and finite nuclear size have also been neglected. ^[ref]

A three-level laser uses a pump transition from ground level1 to a higher level3, rapid relaxation $3\to 2$, and a long-lived upper lasing level2. The laser transition is $2\to 1$, so its lower level is the ground state. Fast feeding and slow upper-state decay allow excitation to accumulate, unlike steady resonant pumping of a simple two-level transition.

Stimulated emission adds photons to the stimulating optical mode, but ground-state photon absorption competes with it. The population inversion condition is $N_2/g_2>N_1/g_1$ when the relevant transition strengths obey the usual Einstein relations. For equal degeneracies and negligible $N_3$, it reduces to $N_2>N_1$, requiring more than half the active population in level2.

For a simple pump rate R per ground-state emitter, fast $3\to 2$ relaxation and negligible laser intensity, the three-level laser rate equation reduces toThis three-level ground-state inversion threshold is only transparency; positive gain must also overcome optical losses. For an illustrative uniformly filled cavity of length $\ell$, equal absorption/emission cross-section $\sigma$, internal intensity-loss coefficient ${\alpha }_i$ and mirror power reflectivities $R_1,R_2$, the threshold condition isHere $n_i$ are number densities, unlike the total populations $N_i$. The optical resonator supplies feedback and selects modes; a partially transmitting mirror couples out light. Spontaneous emission seeds the field, and stimulated transitions deplete the inversion until saturated gain balances loss. A ruby laser is the standard example. Real level degeneracies, branching losses and pump saturation modify the simple equations. ^[ref]